682705
Chloro(tri-tert-butylphosphine)gold(I)
Synonym(s):
(Tri-tert-butylphosphine)chlorogold, (Tri-tert-butylphosphine)gold(I) chloride, (tBu3P)AuCl
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About This Item
Linear Formula:
(C4H9)3PAuCl
CAS Number:
Molecular Weight:
434.74
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
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form
solid
reaction suitability
core: gold
reagent type: catalyst
mp
>300 °C
SMILES string
Cl[Au].CC(C)(C)P(C(C)(C)C)C(C)(C)C
InChI
1S/C12H27P.Au.ClH/c1-10(2,3)13(11(4,5)6)12(7,8)9;;/h1-9H3;;1H/q;+1;/p-1
InChI key
JLXSZGSXDDQSJF-UHFFFAOYSA-M
Application
Gold Catalysts — 21st Century ′Gold Rush′
- Useful catalyst in a variety of C-C bond forming reactions, including cyclopropanation.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Oral
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Customers Also Viewed
Toste, F.D. et al.
Journal of the American Chemical Society, 172, 18002-18002 (2005)
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