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Key Documents

407518

Sigma-Aldrich

Julolidine hydrobromide

97%

Synonym(s):

2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizine hydrobromide

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About This Item

Empirical Formula (Hill Notation):
C12H15N · HBr
CAS Number:
Molecular Weight:
254.17
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

form

powder

mp

239-242 °C (lit.)

SMILES string

Br.C1CN2CCCc3cccc(C1)c23

InChI

1S/C12H15N.BrH/c1-4-10-6-2-8-13-9-3-7-11(5-1)12(10)13;/h1,4-5H,2-3,6-9H2;1H

InChI key

KHWBRFVBPGPEOJ-UHFFFAOYSA-N

General description

Julolidines are effective auxofluors that are employed in laser dyes and biochemical stains. They are known to be one of the strongest electron-releasing groups due to electronic and steric factors.

Application

Julolidine hydrobromide may be used in the synthesis of [4-(2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinolin-9-ylazo)-phenyl]-methanol azodye.

Pictograms

CorrosionSkull and crossbones

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis, optical characterization and crystal and molecular X-ray structure of a phenylazojulolidine derivative.
Barbero N, et al.
Dyes and Pigments, 92(3), 1177-1183 (2012)
Synthesis of julolidine derivatives.
Kauffman JM, et al.
Organic preparations and procedures international, 33(6), 603-613 (2001)

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