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Sigma-Aldrich

Perfluoro(methyldecalin), mixture of isomers

technical grade, 80%

Synonym(s):

Heptadecafluorodecahydro(trifluoromethyl)naphthalene

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About This Item

Empirical Formula (Hill Notation):
C11F20
CAS Number:
51294-16-7
Molecular Weight:
512.09
UNSPSC Code:
12352100
PubChem Substance ID:
24863035
NACRES:
NA.22

grade

technical grade

Quality Level

100

Assay

80%

form

liquid

refractive index

n20/D 1.317 (lit.)

bp

137-160 °C (lit.)

mp

−40 °C (lit.)

density

1.95 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C1(F)C(F)(F)C(F)(F)C2(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C2(F)C1(F)F.FC(F)(F)C3(F)C(F)(F)C(F)(F)C(F)(F)C4(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C34F

InChI

1S/C11F20/c12-1-2(13,6(19,20)10(27,28)9(25,26)4(1,15)16)5(17,18)8(23,24)7(21,22)3(1,14)11(29,30)31

InChI key

LWRNQOBXRHWPGE-UHFFFAOYSA-N

Related Categories

General description

Perfluoro(methyldecalin) is a fluorinated solvent.

Application

Perfluoro(methyldecalin is suitable reagent used to investigate the reactions of iodide anions and anions derived from glow discharge ionization of perfluoro(methyldecalin) with positive ions derived from poly(ethylene glycol). It is suitable reagent used for the oxidation of alcohols with the ruthenium porphyrin at higher temperatures (140ºC) and elevated oxygen pressures (50psi). Perfluoro(methyldecalin (Perfluoro-1-Methyldecalin) may be used in the preparation of undecafluoro-6-trifluoromethyltetralin via defluorination.

Other Notes

Contains perfluorodecalin

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

235.0 °F - closed cup

Flash Point(C)

112.80 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Perfluoro-1-methyldecalin as a potential oxygen carrier with fluid scleral lenses.
M F Refojo et al.
Current eye research, 4(6), 732-733 (1985-06-01)
Michinao Hashimoto et al.
Small (Weinheim an der Bergstrasse, Germany), 3(10), 1792-1802 (2007-09-25)
A method is described for the formation of stable, composite aqueous emulsions of 1) combinations of distinct families of bubbles of nitrogen, 2) combinations of distinct families of droplets of an organic fluid (either perfluoro(methyl)decalin or hexadecane), and 3) combinations
M K Bakulin et al.
Mikrobiologiia, 75(3), 371-376 (2006-07-29)
The isolates of pseudomonads (56) and of Plesiomonas shigelloides (7) exhibiting ice-forming activity were isolated from plant leaves and rhizosphere. The theoretical possibility of the application of perfluorocarbons (PFC) with a gas-transporting function (perfluorodecalin, carbogal, and perfluoromethyldecalin) for the cultivation
Reactions of poly (ethylene glycol) cations with iodide and perfluorocarbon anions.
Stephenson Jr JM and McLuckey SA.
Journal of the American Society For Mass Spectrometry, 9(9), 957-965 (1998)
D J McIver et al.
Biochimica et biophysica acta, 751(1), 74-80 (1983-03-22)
An effective substitute for pulmonary surfactant must be able to reduce water-vapour surface tensions to under 1 mN/m and it must spread rapidly and spontaneously at the air interface from the aqueous phase. Pure dipalmitoylphosphatidylcholine meets the former requirement, but
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