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Sigma-Aldrich

Hoveyda-Grubbs Catalyst® M721 ChemBeads

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Synonym(s):

Hoveyda-Grubbs Catalyst®M72 SI(o-Tol) (C571)

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About This Item

Empirical Formula (Hill Notation):
C27H30Cl2N2ORu
CAS Number:
Molecular Weight:
570.52
UNSPSC Code:
12352300

form

solid

Quality Level

composition

, 4-6 wt. % (loading of catalyst)

reaction suitability

reagent type: catalyst
core: ruthenium
reaction type: Ring-Opening Polymerization

SMILES string

Cl[Ru](C1N(C2=CC=CC=C2C)CCN1C3=CC=CC=C3C)(O4C(C)C)(Cl)=CC5=C4C=CC=C5

InChI

1S/C17H19N2.C10H12O.2ClH.Ru/c1-14-7-3-5-9-16(14)18-11-12-19(13-18)17-10-6-4-8-15(17)2;1-8(2)11-10-7-5-4-6-9(10)3;;;/h3-10,13H,11-12H2,1-2H3;3-8H,1-2H3;2*1H;/q;;;;+2/p-2

InChI key

AFQRYTARHOMPFY-UHFFFAOYSA-L

General description

Less sterically hindered analog of Hoveyda-Grubbs Catalyst® 2nd Generation. Excels at ring-closing metathesis reactions of sterically encumbered olefins. Also useful for the cross metathesis of olefins bearing large allylic substituents. ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Legal Information

Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

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