74567

Permethrin-(phenoxy-d₅)

mixture of cis and trans isomers, PESTANAL^®, analytical standard

• Synonym(s): Permethrin-d₅, [3-(Phenoxy-d₅)phenyl]methyl 2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropanecarboxylate
• Empirical Formula (Hill Notation): C₂₁D₅H₁₅Cl₂O₃
• CAS Number: 1794760-19-2
• Molecular Weight: 396.32
• UNSPSC Code: 12352200
• NACRES: NA.24

Properties

• grade: analytical standard
• Quality Level: 100
• product line: PESTANAL^®
• Assay: ≥98.0% (sum of isomers, HPLC)
• shelf life: limited shelf life, expiry date on the label
• format: neat

Description

General description

Permethrin-(phenoxy-d₅) is an isotope labeled analog of the pyrethroid insecticide permethrin, wherein the five phenoxy protons are replaced by deuterium.

Application

Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis, potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS07,GHS09
• Signal Word: Warning
• Hazard Statements: H302 + H332 - H317 - H410
• Precautionary Statements: P261 - P273 - P280 - P301 + P312 - P302 + P352 - P304 + P340 + P312
• Hazard Classifications: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable