B52808
1,2-Di(4-pyridyl)ethylene
97%
Synonym(s):
1,2-Bis(4-pyridyl)ethylene, 4,4′-Vinylenedipyridine
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About This Item
Empirical Formula (Hill Notation):
C12H10N2
CAS Number:
Molecular Weight:
182.22
Beilstein:
3865
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
97%
form
crystals
mp
148-152 °C (lit.)
SMILES string
c1cc(ccn1)\C=C\c2ccncc2
InChI
1S/C12H10N2/c1(11-3-7-13-8-4-11)2-12-5-9-14-10-6-12/h1-10H/b2-1+
InChI key
MGFJDEHFNMWYBD-OWOJBTEDSA-N
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Application
1,2-Di(4-pyridyl)ethylene is extensively used as a ligand/linker in the synthesis of a variety of metal-organic frameworks(MOFs) and coordination polymers (CPs). It is employed in the synthesis of:
- Expanding and shrinking cadmium-based pillared layer coordination polymers showing selective guest adsorption.
- Dinuclear zinc complex that exhibits photocontrolled fluorescence.
- Platinum-based 3-D tetragonal prisms via multicomponent coordination-driven self-assembly.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Metallosupramolecular tetragonal prisms via multicomponent coordination-driven template-free self-assembly.
Wang M, et al.
Journal of the American Chemical Society, 132(18), 6282-6283 (2010)
Hydrogen adsorption in an interpenetrated dynamic metal- organic framework.
Chen B, et al.
Inorganic Chemistry, 45(15), 5718-5720 (2006)
Coordination-driven self-assembly directs a single-crystal-to-single-crystal transformation that exhibits photocontrolled fluorescence.
Papaefstathiou GS, et al.
Journal of the American Chemical Society, 126(30), 9158-9159 (2004)
Expanding and Shrinking Porous Modulation Based on Pillared-Layer Coordination Polymers Showing Selective Guest Adsorption.
Maji TK, et al.
Angewandte Chemie (International Edition in English), 43(25), 3269-3272 (2004)
Isoreticular Homochiral Porous Metal- Organic Structures with Tunable Pore Sizes.
Dybtsev DN, et al.
Inorganic Chemistry, 46(17), 6843-6845 (2007)
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