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Key Documents

ALD00430

Sigma-Aldrich

1-Naphthalenyl ester fluorosulfuric acid

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About This Item

Empirical Formula (Hill Notation):
C10H7FO3S
CAS Number:
Molecular Weight:
226.22
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

description

Fp: >230°F

Quality Level

form

liquid

refractive index

n20/D 1.5576

density

1.3674 g/mL at 25 °C

SMILES string

O=S(OC1=CC=CC2=CC=CC=C21)(F)=O

InChI

1S/C10H7FO3S/c11-15(12,13)14-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H

InChI key

GEZWNEDYJCOWLU-UHFFFAOYSA-N

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Application

The following aryl fluorosulfate can be utilized as a cross-coupling partner in Suzuki-Miyaura reactions. The standard reaction conditions for these palladium-catalyzed C-C bond formations are ligand-free and can be performed in water, at room temperature and are not air sensitive.

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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