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335061

Sigma-Aldrich

Ferrocenemethanol

97%

Synonym(s):

FcMeOH, (Hydroxymethyl)ferrocene, Ferrocenylcarbinol

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About This Item

Empirical Formula (Hill Notation):
C11H12FeO
CAS Number:
Molecular Weight:
216.06
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Assay

97%

form

solid

reaction suitability

core: iron
reagent type: catalyst

mp

79-81 °C (lit.)

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.OC[C]2[CH][CH][CH][CH]2

InChI

1S/C6H7O.C5H5.Fe/c7-5-6-3-1-2-4-6;1-2-4-5-3-1;/h1-4,7H,5H2;1-5H;

InChI key

QETISSZVCNFQBN-UHFFFAOYSA-N

Application

  • Ferrocenemethanol (FcMeOH) is commonly used as a water soluble ferrocene based reference redox system in electrochemical studies.
  • It is used in the synthesis of ferrocenylmethoxy-isatins, potent antiproliferative agents.
  • FcMeOH can be employed in the preparation of ferrocene-carbohydrate conjugates for biosensing applications.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Convenient methods for the synthesis of ferrocene? carbohydrate conjugates.
Casas-Solvas J M, et al.
Organic Letters, 6(21), 3687-3690 (2004)
Azide?Alkyne Cycloaddition En Route to 1 H-1, 2, 3-Triazole-Tethered Isatin?Ferrocene, Ferrocenylmethoxy?Isatin, and Isatin?Ferrocenylchalcone Conjugates: Synthesis and Antiproliferative Evaluation.
Singh A, et al.
ACS Omega, 3(1), 1263-1268 (2018)
Graphene?based optically transparent electrodes for spectroelectrochemistry in the UV?Vis region.
Weber C M, et al.
Small, 6(2), 184-189 (2010)
Jingyi Wang et al.
Journal of colloid and interface science, 570, 350-361 (2020-03-18)
Molybdenite (MoS2) has attracted great attention in the field of advanced materials. MoS2 is normally separated from other minerals by selective flotation, and chemical reagents (so-called depressants) are required to lower the surface hydrophobicity of MoS2. Previous studies had controversial
Effect of the mediator in feedback mode-based SECM interrogation of indium tin-oxide and boron-doped diamond electrodes.
Neufeld A K and O?Mullane A P
Journal of Solid State Electrochemistry, 10(10), 808-816 (2006)

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