Skip to Content
Merck
All Photos(3)

Documents

225959

Sigma-Aldrich

Magnesium bromide ethyl etherate

99%

Synonym(s):

Dibromo(1,1′-oxybis(ethane))magnesium, Dibromo(diethyl ether)magnesium, Magnesium bromide diethyl etherate, Magnesium bromide etherate

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
MgBr2 · O(C2H5)2
CAS Number:
Molecular Weight:
258.23
Beilstein:
4937320
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.22

Assay

99%

SMILES string

Br[Mg]Br.CCOCC

InChI

1S/C4H10O.2BrH.Mg/c1-3-5-4-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2

InChI key

JGZKUKYUQJUUNE-UHFFFAOYSA-L

Looking for similar products? Visit Product Comparison Guide

Application

Magnesium bromide ethyl etherate can be used as a reagent:
  • In the Lewis acid-catalyzed Diels-Alder reactions.
  • For the conversion of aromatic aldehydes into alcohols and carboxylic acids via Cannizzaro reaction.

Pictograms

Flame

Signal Word

Danger

Hazard Statements

Hazard Classifications

Flam. Sol. 1 - Water-react 2

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Tetrahedron Asymmetry, 2, 1193-1193 (1991)
Room-temperature Cannizzaro reaction under mild conditions facilitated by magnesium bromide ethyl etherate and triethylamine
Abaee M, et al.
Organic Letters, 7, 5893-5895 (2005)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service