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Silver-mediated fluorination of aryl silanes.

Tetrahedron (2011-06-22)
Pingping Tang, Tobias Ritter
PMID21691436
ABSTRACT

A regiospecific silver-mediated fluorination of aryl silanes is reported. The reaction is operationally simple, and employs Ag(2)O as readily available, inexpensive silver source, which can be recovered.

MATERIALS
Product Number
Brand
Product Description
640360
Sigma-Aldrich
Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate
128392
Sigma-Aldrich
1-Fluoro-3-nitrobenzene, 97%