673935

Chlorodiphenylsilane

technical grade, 90%

• Synonym(s): Diphenylchlorosilane
• Linear Formula: (C₆H₅)₂SiHCl
• CAS Number: 1631-83-0
• Molecular Weight: 218.75
• Beilstein: 2937164
• MDL number: MFCD00045144
• UNSPSC Code: 12352002
• PubChem Substance ID: 24885189
• NACRES: NA.22

Properties

• grade: technical grade
• Assay: 90%
• refractive index: n20/D 1.578 (lit.)
• bp: 143 °C/10 mmHg (lit.)
• density: 1.118 g/mL at 25 °C (lit.)
• SMILES string: [H][Si](Cl)(c1ccccc1)c2ccccc2
• InChI: 1S/C12H11ClSi/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,14H
• InChI key: VTMOWGGHUAZESJ-UHFFFAOYSA-N

Description

General description

Chlorodiphenylsilane is an organosilicon compound that can be used as a protecting group for alcohols and amines. It is also used as a reagent in cross-coupling reactions. In addition, it is used as a precursor in the synthesis of various silicon-containing compounds.

Application

Chlorodiphenylsilane can be used as a reactant for the selective mono- and di-allylation and allenylation of chlorosilanes in the presence of indium/base to synthesize mono- or di-allylated or allenylation products. It also acts as a responsive coupling agent for functionalizing silica surfaces.

Safety Information

• Pictograms: GHS05
• Signal Word: Danger
• Hazard Statements: H314
• Precautionary Statements: P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405
• Hazard Classifications: Eye Dam. 1 - Skin Corr. 1B
• Supplementary Hazards: EUH014
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 1
• Flash Point(F): 221.0 °F
• Flash Point(C): 105 °C