442593

Tris(pentafluorophenyl)borane

95%

• Synonym(s): Perfluorotriphenylboron
• Linear Formula: (C₆F₅)₃B
• CAS Number: 1109-15-5
• Molecular Weight: 511.98
• MDL number: MFCD00269813
• UNSPSC Code: 12352300
• PubChem Substance ID: 24867921
• NACRES: NA.23

Properties

• Quality Level: 100
• Assay: 95%
• form: powder
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• mp: 126-131 °C (lit.)
• greener alternative category: Aligned,
• SMILES string: Fc1c(F)c(F)c(B(c2c(F)c(F)c(F)c(F)c2F)c3c(F)c(F)c(F)c(F)c3F)c(F)c1F
• InChI: 1S/C18BF15/c20-4-1(5(21)11(27)16(32)10(4)26)19(2-6(22)12(28)17(33)13(29)7(2)23)3-8(24)14(30)18(34)15(31)9(3)25
• InChI key: OBAJXDYVZBHCGT-UHFFFAOYSA-N

Description

General description

B(C₆F₅)₃ is a Lewis acid, stronger than the inorganic parent molecule BF₃. In contrast to the prominent Lewis acids, the pentafluorides of the heavier elements of group 15, B(C₆F₅)₃ has no oxidizing properties. B(C₆F₅)₃ forms adducts with neutral and weaker Lewis bases. B(C₆F₅)₃ has the capability to easily accept anionic ligands bonded to metals.

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Application

A versatile reagent widely used in the preparation of d⁰ arene and other organometallic complexes useful as polymerization catalysts.
Used with tri-tert-butylphosphine (570958) to study the heterolytic cleavage of dihydrogen at room temperature and one atmosphere pressure.

Features and Benefits

A versatile reagent widely used in the preparation of d⁰ arene and other organometallic complexes useful as polymerization catalysts.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315 - H319 - H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves