377155
Chlorobis(cyclooctene)iridium(I)dimer
97%
Synonym(s):
[Ir(coe)2Cl]2, Di-μ-chlorotetrakis(cyclooctene)diiridium
About This Item
Recommended Products
Assay
97%
form
powder
reaction suitability
core: iridium
reagent type: catalyst
mp
160-165 °C (dec.) (lit.)
SMILES string
Cl[Ir].Cl[Ir].[CH]1[CH]CCCCCC1.[CH]2[CH]CCCCCC2.[CH]3[CH]CCCCCC3.[CH]4[CH]CCCCCC4
InChI
1S/4C8H14.2ClH.2Ir/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;
InChI key
WBRREXQCZAFSKS-XFCUKONHSA-L
Related Categories
Application
- Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand
- Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions
- Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions
- Alkylation reactions
- Guerbet reaction
- Allylic amination reactions in a DNA-diene-iridium(I) hybrid system
- Asymmetric hydroamination reactions
- Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand.
- Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions.
- Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions.
- Alkylation reactions.
- Guerbet reaction.
- Allylic amination reactions using a DNA-diene-iridium(I) hybrid system.
- Asymmetric hydroamination reactions.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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Arylboronic acids and esters are invaluable tools for the chemical community. These powerful reagents are used for a variety of transformations, most notably the Suzuki-Miyaura cross-coupling reaction.
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