Skip to Content
Merck
All Photos(3)

Documents

376876

Sigma-Aldrich

N-Methoxy-N-methyl(triphenylphosphoranylidene)acetamide

98%

Synonym(s):

(N-Methoxymethylaminocarbonylmethylene)triphenylphosphorane

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
(C6H5)3P=CHCON(OCH3)CH3
CAS Number:
Molecular Weight:
363.39
Beilstein:
4198472
MDL number:
UNSPSC Code:
12352002
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

reaction suitability

reaction type: C-C Bond Formation

mp

173-175 °C (lit.)

SMILES string

CON(C)C(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C22H22NO2P/c1-23(25-2)22(24)18-26(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21/h3-18H,1-2H3

InChI key

DGBLSOOPDBHHRX-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Application

Reactant for:
  • Synthesis of electron-deficient alkenes via stereoselective olefination of N-sulfonyl imines
  • Phosphine-catalyzed asymmetric addition reactions
  • Cysteine-catalyzed enantioselective intramolecular Rauhut-Currier reaction
  • Wittig olefination
  • Synthesis of aigialomycin D, a Protein Kinase inhibitor and a potential anticancer agent

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service