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Sigma-Aldrich

1,2-Bis(dimethylphosphino)ethane

97%

Synonym(s):

DMPE, Dimethyl-2-(dimethylphosphino)ethylphosphine, Ethylenebis(dimethylphosphine)

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About This Item

Linear Formula:
(CH3)2PCH2CH2P(CH3)2
CAS Number:
23936-60-9
Molecular Weight:
150.14
Beilstein:
1732994
MDL number:
MFCD00008511
UNSPSC Code:
12352001
PubChem Substance ID:
24855844
NACRES:
NA.22

Assay

97%

form

liquid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

refractive index

n20/D 1.507 (lit.)

bp

180 °C (lit.)

density

0.9 g/mL at 25 °C (lit.)

functional group

phosphine

SMILES string

CP(C)CCP(C)C

InChI

1S/C6H16P2/c1-7(2)5-6-8(3)4/h5-6H2,1-4H3

InChI key

ZKWQSBFSGZJNFP-UHFFFAOYSA-N

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General description

1,2-Bis(dimethylphosphino)ethane (dmpe) is a polydentate phosphine ligand. Synthesis of 1,2-bis(dimethylphosphino)ethane has been reported. It reacts with ZrCl2 to afford ZrCl4(dmpe)2 complexes.

Application

1,2-Bis(dimethylphosphino)ethane (dmpe) may be employed as ligand in the preparation of cis-arylmethyl(dmpe) nickel(II) complexes.

accessory

Product No.
Description
Pricing

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Danger

Hazard Statements

H225,H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ7158
MKCM9059
MKCM5542
MKCM6108
MKCM6107

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A convenient synthesis of 1, 2-bis (dichlorophosphino) ethane, 1, 2-bis (dimethylphosphino) ethane and 1,2-bis (diethylphosphino) ethane.
Burt RJ, et al.
Journal of Organometallic Chemistry, 182(2), 203-206 (1979)
Beatty RP, et al.
Inorganic Chemistry, 18(11), 3139-3145 (1979)
M Suwalsky et al.
Biochimica et biophysica acta, 1848(11 Pt A), 2829-2838 (2015-08-25)
Usnic acid (UA) has been associated with chronic diseases through its antioxidant action. Its main target is the cell membrane; however, its effect on that of human erythrocytes has been scarcely investigated. To gain insight into the molecular mechanisms of
Phosphine-induced reductive elimination from cis-arylmethylnickel (II) complexes having a 1,2-bis(dimethylphosphino) ethane ligand
Komiya S, et al.
Organometallics, 2(10), 1466-1468 (1983)
Mario Suwalsky et al.
The Journal of membrane biology, 248(4), 683-693 (2015-03-01)
Despite the extended use and well-documented information, there are insufficient reports concerning the effects of propranolol on the structure and functions of cell membranes, particularly those of human erythrocytes. Aimed to better understand the molecular mechanisms of its interactions with
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