177199
Methyl propargyl ether
≥97%
Synonym(s):
3-Methoxy-1-propyne, Methyl 2-propynyl ether
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About This Item
Linear Formula:
HC≡CCH2OCH3
CAS Number:
Molecular Weight:
70.09
Beilstein:
878166
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
≥97%
form
liquid
refractive index
n20/D 1.396 (lit.)
bp
61-62 °C (lit.)
density
0.83 g/mL at 25 °C (lit.)
functional group
ether
storage temp.
2-8°C
SMILES string
COCC#C
InChI
1S/C4H6O/c1-3-4-5-2/h1H,4H2,2H3
InChI key
YACFFSVYSPMSGS-UHFFFAOYSA-N
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General description
The Raman spectra of methyl propargyl ether has been studied.
Application
Methyl propargyl ether was used in the synthesis of [Ru3(μ3-κ(2)-HNNMe2)(μ3-κ(2)-MeOCH2CCH2)(μ-CO)2(CO)6].
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
-0.4 °F - closed cup
Flash Point(C)
-18 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Javier A Cabeza et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 11(20), 6040-6052 (2005-07-30)
The reactions of the hydrido-triruthenium cluster complex [Ru3(mu-H)(mu3-kappa(2)-HNNMe2)(CO)9] (1; H2NNMe2 = 1,1-dimethylhydrazine) with alkynes that have alpha-hydrogen atoms give trinuclear derivatives containing edge-bridging allyl or face-capping alkenyl ligands. Under mild conditions (THF, 70 degrees C) the isolated products are as
Conformational stability, barriers to internal rotation, ab initio calculations and vibrational assignment of methyl propargyl ether.
Journal of Molecular Structure, 320, 193-216 (1994)
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