701211

Acetylacetonatobis(ethylene)rhodium(I)

95%

• Synonym(s): (2,4-Pentanedionato)bis(ethylene)rhodium, Bis(η²-ethene)(2,4-pentanedionato-κO,κO′)rhodium, Bis(ethylene)(2,4-pentanedionato)rhodium, Bis(ethylene)rhodium(I) acetylacetonate, Diethylene(acetylacetonato)rhodium
• Empirical Formula (Hill Notation): C₉H₁₅O₂Rh
• CAS Number: 12082-47-2
• Molecular Weight: 258.12
• EC Number: 235-147-1
• MDL number: MFCD00015354
• UNSPSC Code: 12161600
• PubChem Substance ID: 329762272
• NACRES: NA.22

Properties

• Assay: 95%
• form: solid
• reaction suitability: core: rhodium; reagent type: catalyst
• mp: 141-142 °C
• storage temp.: 2-8°C
• SMILES string: C=C.C=C.CC(=O)\C=C(\C)O[Rh]
• InChI: 1S/C5H8O2.2C2H4.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;2*1-2H2;/q;;;+1/p-1/b4-3-;;;
• InChI key: FLRBEQQDEGBCJS-FGSKAQBVSA-M

Description

General description

Acetylacetonatobis(ethylene)rhodium(I) is a coordination compound commonly used as a precursor to synthesize mononuclear rhodium complexes. In addition, it is also used as a catalyst in asymmetric arylation reactions.

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves