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524328

Sigma-Aldrich

5-Iodosalicylaldehyde

97%

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About This Item

Linear Formula:
lC6H3(OH)CHO
CAS Number:
Molecular Weight:
248.02
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

97%

mp

98-100 °C (lit.)

functional group

aldehyde
iodo

SMILES string

Oc1ccc(I)cc1C=O

InChI

1S/C7H5IO2/c8-6-1-2-7(10)5(3-6)4-9/h1-4,10H

InChI key

PDFVIWFKGYODKD-UHFFFAOYSA-N

General description

5-Iodosalicylaldehyde is a salicylaldehyde derivative.

Application

5-Iodosalicylaldehyde may be used to synthesize:
  • 5-formylsalicylaldehyde
  • 5-ortho-carboranylsalicylaldehyde
  • new salen (N,N′-Bis(salicylidene)ethylenediamine) ligands that are tethered to a p-acylthio(phenylacetylene)n linker

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Synthesis of 5-ortho-Carboranylsalicylaldehyde and an Indolinospirobenzopyran.
Lee SH, et al.
Synthetic Communications, 39(22), 4069-4078 (2009)
Synthesis and catalytic properties of p-acylthio (phenylacetylene) n substituted chiral manganese salen complexes.
Nielsen M and Gothelf KV.
Journal of the Chemical Society. Perkin Transactions 1, 19 (2001)
An efficient and convenient synthesis of 5-formylsalicylaldehyde.
Lee SH, et al.
Synthetic Communications, 30(6), 1003-1008 (2000)

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