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449857

Sigma-Aldrich

Lanthanum(III) fluoride

anhydrous, powder, 99.99% trace metals basis

Synonym(s):

Lanthanum fluoride, Lanthanum trifluoride

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About This Item

Linear Formula:
LaF3
CAS Number:
Molecular Weight:
195.90
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

grade

anhydrous

Assay

99.99% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: lanthanum

impurities

≤200.0 ppm Trace Rare Earth Analysis

density

5.936 g/mL at 25 °C (lit.)

SMILES string

F[La](F)F

InChI

1S/3FH.La/h3*1H;/q;;;+3/p-3

InChI key

BYMUNNMMXKDFEZ-UHFFFAOYSA-K

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Application

Employed extensively in the preparation and study of fluoride glasses.

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Daibo Pi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 61(11-12), 2455-2459 (2005-07-27)
Europium-doped LaF3 nanoparticles have been prepared by the ionic reaction in the ethanol at 60 degrees C. From the XRD pattern of nanoparticles and the emission spectra of Eu3+ ions, it has been concluded that the Eu3+ ions could easily
Nadine Häntzschel et al.
Langmuir : the ACS journal of surfaces and colloids, 23(21), 10793-10800 (2007-09-15)
We describe the synthesis and properties of functional microgel particles based on poly(N-vinylcaprolactam-co-glycidyl methacrylate) (PVCL/PGMA) copolymer. A series of colloidally stable microgel particles with a range of glycidyl methacrylate content were prepared by surfactant-free heterophase polymerization in water. The microgel
Andy Y H Lo et al.
Journal of the American Chemical Society, 129(15), 4687-4700 (2007-03-28)
Multinuclear solid-state NMR spectroscopy and powder X-ray diffraction (XRD) experiments are applied to comprehensively characterize a series of pure and lanthanide-doped LaF3 nanoparticles (NPs) that are capped with di-n-octadectyldithiophosphate ligands (Ln3+ = diamagnetic Y3+ and Sc3+ and paramagnetic Yb3+ ions)
Jian-Xin Meng et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 66(1), 81-85 (2006-07-04)
LaF3:Eu3+ nanoparticles were prepared by a simple hydrothermal process at low temperature and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and fluorescence spectrum. Well-dispersed nanoparticles with an average size of 30 nm and a hexagonal shape were obtained.
Radiative lifetime modification of LaF₃:Nd nanoparticles embedded in 3D silicon photonic crystals.
Hailong Ning et al.
Advanced materials (Deerfield Beach, Fla.), 24(23), OP153-OP158 (2012-05-10)

Articles

The rare earth elements impact nearly everyone in the world. All of the people living in advanced technological countries and almost all those living in third world countries utilize the rare earths in their everyday living—the car that one drives (gasoline is refined from oil using rare earth catalysts and catalytic converters reduce the polluting emissions from the automotive exhaust), watching the news on TV (the red and green colors in TV screens), the telephones and computers we use to communicate (the permanent magnets in speakers and disc drives), just to name a few examples.

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