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32784

Sigma-Aldrich

4,4′-Ethylenedianiline

technical, ≥95% (NT)

Synonym(s):

α,α′-Bi-p-toluidine, 4,4′-Diaminobibenzyl

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About This Item

Empirical Formula (Hill Notation):
C14H16N2
CAS Number:
621-95-4
Molecular Weight:
212.29
Beilstein:
394999
EC Number:
210-716-7
MDL number:
MFCD00007923
UNSPSC Code:
12352100
PubChem Substance ID:
57648725
NACRES:
NA.22

grade

technical

Assay

≥95% (NT)

form

solid

mp

133-137 °C (lit.)

application(s)

diagnostic assay manufacturing
hematology
histology

storage temp.

room temp

SMILES string

Nc1ccc(CCc2ccc(N)cc2)cc1

InChI

1S/C14H16N2/c15-13-7-3-11(4-8-13)1-2-12-5-9-14(16)10-6-12/h3-10H,1-2,15-16H2

InChI key

UHNUHZHQLCGZDA-UHFFFAOYSA-N

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Application

4,4′-Ethylenedianiline may be used as an internal standard for the determination of 4,4′-methylenedianiline in urine samples using gas chromatography coupled with mass spectrometry (GC-MS).
4,4′-Ethylenedianiline was used in preparation of molecularly imprinting sol-gel materials for detection of DDT.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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[Determination of the carcinogenic risk of diaminodibenzyl (DADB)].
M Balan et al.
Revista medico-chirurgicala a Societatii de Medici si Naturalisti din Iasi, 84(3), 521-525 (1980-07-01)
X Wu et al.
Se pu = Chinese journal of chromatography, 16(6), 536-538 (2002-04-10)
A method for simultaneous determination of trace 4,4'-diaminobiphenyl, 4-nitrophenol and phenol in waste water by high performance liquid chromatography with spectrophotometric detection is reported. These components were separated on a Phenomenex Spherex C18 column with V(acetonitrile): V(ether): V(50 mmol.L-1 acetate)
High-performance liquid chromatographic determination of 4,4?-methylenedianiline in human urine.
Peterson JC, et al.
Journal of Chromatography. B, Biomedical Sciences and Applications, 564(1), 205-212 (1991)
Amy L Graham et al.
Analytical chemistry, 74(2), 458-467 (2002-01-29)
Molecularly imprinting sol-gel materials for DDT using both a noncovalent and a covalent approach was examined. A nonpolar porous sol-gel network was created through the use of the bridged polysilsesquioxane, bis-(trimethoxysilylethyl)benzene (BTEB), as the principal sol-gel component. Noncovalent molecular imprinting
Petros Giastas et al.
Acta crystallographica. Section B, Structural science, 59(Pt 2), 287-299 (2003-03-27)
The present investigation is part of an ongoing study on the influence of the long end-functonalized guest molecules DBA and BNZ in the crystal packing of beta-cyclodextrin (betaCD) dimeric complexes. The title compounds are 2:2 host:guest complexes showing limited host-guest
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