209015
Palladium(II) acetylacetonate
99%
Synonym(s):
Palladium(II) 2,4-pentanedionate, Pd(acac)2
About This Item
Recommended Products
Quality Level
Assay
99%
form
powder
reaction suitability
core: aluminum
reagent type: catalyst
mp
200-251 °C (dec.)
SMILES string
CC(=O)\C=C(\C)O[Pd]O\C(C)=C/C(C)=O
InChI
1S/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
InChI key
JKDRQYIYVJVOPF-FDGPNNRMSA-L
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General description
Application
- Typical high-temperature organic solution phase protocol for the preparation of monodisperse CuPd alloy nanoparticles (NPs).
- Preparation of [(NHC)Pd(acac)L] (where L=Me, NHC = N-heterocyclic carbene) complexes. These complexes efficiently catalyze the Heck reaction of activated aryl bromides.
- As catalyst in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes and aryl or vinyl halides (or triflates) to afford substituted alkenes.
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