108707
2-Methyl-3-pentanone
97%
Synonym(s):
Ethyl isopropyl ketone
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About This Item
Linear Formula:
(CH3)2CHCOC2H5
CAS Number:
Molecular Weight:
100.16
Beilstein:
1698849
EC Number:
MDL number:
UNSPSC Code:
12352100
eCl@ss:
39021212
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
refractive index
n20/D 1.397 (lit.)
bp
113 °C (lit.)
density
0.811 g/mL at 25 °C (lit.)
functional group
ketone
SMILES string
CCC(=O)C(C)C
InChI
1S/C6H12O/c1-4-6(7)5(2)3/h5H,4H2,1-3H3
InChI key
HYTRYEXINDDXJK-UHFFFAOYSA-N
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Application
2-Methyl-3-pentanone may be used to study the stereochemistry of ketone enolization by lithium 2, 2, 6, 6-tetramethylpiperidide.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Liq. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
51.8 °F - closed cup
Flash Point(C)
11 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Effects of lithium salts on the stereochemistry of ketone enolization by lithium 2, 2, 6, 6-tetramethylpiperidide (LiTMP). A convenient method for highly E-selective enolate formation.
Hall PL, et al.
Journal of the American Chemical Society, 113(25), 9571-9574 (1991)
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