07313

Demeton-S-methyl-sulfon

certified reference material, TraceCERT^®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

• Empirical Formula (Hill Notation): C₆H₁₅O₅PS₂
• CAS Number: 17040-19-6
• Molecular Weight: 262.28
• Beilstein: 1712536
• MDL number: MFCD00055415
• UNSPSC Code: 41116107
• NACRES: NA.24

Properties

• grade: certified reference material; TraceCERT^®
• Quality Level: 300
• product line: TraceCERT^®
• shelf life: limited shelf life, expiry date on the label
• manufacturer/tradename: Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
• format: neat
• storage temp.: 2-8°C
• SMILES string: CCS(=O)(=O)CCSP(=O)(OC)OC
• InChI: 1S/C6H15O5PS2/c1-4-14(8,9)6-5-13-12(7,10-2)11-3/h4-6H2,1-3H3
• InChI key: PZIRJMYRYORVIT-UHFFFAOYSA-N

Description

General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ. Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate. Download your certificate at: http://www.sigma aldrich.com

Demeton-S-methyl sulfone is an insecticide that belongs to the class of organophosphorus compounds, the major group of pest controllers used in agricultural production.

As per Regulation (EC) No 1107/2009, demeton-S-methyl-sulfon is not approved for use in European Union. Maximum residue levels (MRLs) have been set according to Regulation (EU) No 889/2012 for oxydemeton-methyl as a sum of oxydemeton-methyl and Demeton-S-methylsulfone expressed as oxydemeton-methyl for various products of plant and animal origin from 0.01 to 0.05 mg/kg.

Application

It is intended to be used as a certified reference material (CRM) for calibration in chromatography and other analytical techniques. Demeton-S-methyl sulfone CRM may also find its use as described below:

• Validation of a method to monitor 11 organophosphorus residues in samples of banana, papaya, and bell pepper using QuEChERS extraction and high performance liquid chromatography with tandem mass spectrometry (HPLC-MS/MS)(1)
• Simultaneous determination of four pesticides, aldicarb, demeton-S-methyl, fenamiphos, and methiocarb and their metabolites in grape juices using solid-phase extraction and liquid chromatography-tandem mass spectrometry (LC-MS/MS)
• Quantification and confirmation of 16 priority pesticides in baby foods and their comparison using HPLC-MS/MS and UPLC-MS/MS coupled with tandem quadrupole mass spectrometry
• Development of reversed phase liquid chromatography-electrospray ionization-tandem mass spectrometry method for the determination of 52 pesticides in tobacco
• Validation of two variations of the QuEChERS method for the determination of 120 pesticides and metabolites in cereal-based infant foods by LC-MS/MS with electrospray interface (ESI)

Recommended products

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Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS06,GHS09
• Signal Word: Danger
• Hazard Statements: H300 + H330,H311,H411
• Precautionary Statements: P260 - P264 - P273 - P280 - P302 + P352 + P312 - P304 + P340 + P310
• Hazard Classifications: Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Chronic 2
• Storage Class Code: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 2
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable