89320
1-Hexyl-3-methylimidazolium hexafluorophosphate
≥97.0% (HPLC)
Synonym(s):
HMIMPF6
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About This Item
Empirical Formula (Hill Notation):
C10H19F6N2P
CAS Number:
Molecular Weight:
312.24
Beilstein:
8955409
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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description
electrochemical window 5.5 V
Quality Level
Assay
≥97.0% (HPLC)
form
liquid
refractive index
n20/D 1.419
SMILES string
F[P-](F)(F)(F)(F)F.CCCCCCn1cc[n+](C)c1
InChI
1S/C10H19N2.F6P/c1-3-4-5-6-7-12-9-8-11(2)10-12;1-7(2,3,4,5)6/h8-10H,3-7H2,1-2H3;/q+1;-1
InChI key
YPWSSSRXUOQNMQ-UHFFFAOYSA-N
General description
1-Hexyl-3-methylimidazolium hexafluorophosphate is a water-immiscible imidazolium-type room temperature ionic liquid (RTIL) suitable for electrochemistry.
https://www.sigmaaldrich.com/content/dam/sigma-aldrich/materials-science/material-matters/material_matters_v4n4.pdf#page=18
Application
HMIMPF6 can be used as a chelate extraction solvent for divalent metal cations using 4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedione (thenoyltrifluoroacetone, Htta) as an extractant.
Other Notes
Ionic liquid employed in Friedel-Crafts alkylation of aromatic compounds; polarity of salt.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Viscosity of 1-hexyl-3-methylimidazolium hexafluorophosphate and 1-octyl-3-methylimidazolium hexafluorophosphate at high pressure
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Journal of Chemical and Engineering Data, 52.2, 577-579 (2007)
Effect of water, methanol, and acetonitrile on solvent relaxation and rotational relaxation of coumarin 153 in neat 1-hexyl-3-methylimidazolium hexafluorophosphate
Chakrabarty, Debdeep, et al.
The Journal of Physical Chemistry A, 109.9, 1764-1769 (2005)
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The conditions of heating, ionic liquid-based ultrasonic-assisted extraction combined with reverse-phase high performance liquid chromatography were optimized to simultaneously isolate and determinate brazilin and protosappanin B in Caesalpinia sappan. Ionic liquids, including [BMIM]Br, [BMIM]BF
High-pressure phase behavior of systems with ionic liquids: Part III. The binary system carbon dioxide+ 1-hexyl-3-methylimidazolium hexafluorophosphate
Shariati, Alireza, and Cor J. Peters
Journal of Supercritical Fluids, 30.2, 139-144 (2004)
Temperature and Pressure Dependence of the Viscosity of the Ionic Liquids 1-Hexyl-3-methylimidazolium Hexafluorophosphate and 1-Butyl-3-methylimidazolium Bis (trifluoromethylsulfonyl) imide
Harris, Kenneth R., Mitsuhiro Kanakubo, and Lawrence A. Woolf
Journal of Chemical and Engineering Data, 52.3, 1080-1085 (2007)
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