79609

Phosphorus pentoxide

puriss. p.a., ACS reagent, ≥98.0% (T)

• Synonym(s): Phosphoric anhydride, Phosphorus(V) oxide
• Linear Formula: P₂O₅
• CAS Number: 1314-56-3
• Molecular Weight: 141.94
• EC Number: 215-236-1
• UNSPSC Code: 12352300
• PubChem Substance ID: 24887481
• NACRES: NA.21

Properties

• grade: ACS reagent; puriss. p.a.
• Quality Level: 200
• vapor density: 4.9 (vs air)
• vapor pressure: 1 mmHg ( 384 °C); 10 mmHg ( 238 °C)
• Assay: ≥98.0% (T)
• form: powder or crystals
• impurities: ≤0.02% phosphorus trioxide (P₂O₃)
• pH: 1.5 (20 °C, 10 g/L)
• mp: 340 °C (lit.)
• density: 2.3 g/mL at 25 °C (lit.)
• anion traces: chloride (Cl^-): ≤10 mg/kg; nitrate (NO₃^-): ≤5 mg/kg
• cation traces: As: ≤100 mg/kg; Ca: ≤10 mg/kg; Cd: ≤5 mg/kg; Co: ≤5 mg/kg; Cr: ≤5 mg/kg; Cu: ≤5 mg/kg; Fe: ≤5 mg/kg; K: ≤50 mg/kg; Mg: ≤5 mg/kg; Mn: ≤5 mg/kg; NH₄⁺: ≤10 mg/kg; Na: ≤50 mg/kg; Ni: ≤5 mg/kg; Pb: ≤5 mg/kg; Zn: ≤5 mg/kg
• SMILES string: O=P12OP3(=O)OP(=O)(O1)OP(=O)(O2)O3
• InChI: 1S/O10P4/c1-11-5-12(2)8-13(3,6-11)10-14(4,7-11)9-12
• InChI key: YWEUIGNSBFLMFL-UHFFFAOYSA-N

Description

General description

Phosphorus pentoxide (P₂O₅) is a phosphorous oxide. It participates in Pictet-Gams synthesis. Phosphorus pentoxide supported on alumina has been used for solvent-free and microwave-assisted synthesis of 1, 5-benzodiazepine derivatives.

Application

Phosphorus pentoxide may be used in the synthesis of dichlorine heptoxide (Cl₂O₇).

Safety Information

• Pictograms: GHS05
• Signal Word: Danger
• Hazard Statements: H314
• Precautionary Statements: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Eye Dam. 1 - Skin Corr. 1A
• Supplementary Hazards: EUH014
• Storage Class Code: 8B - Non-combustible, corrosive hazardous materials
• WGK: WGK 1
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves