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Key Documents

8.55043

Sigma-Aldrich

IBX polystyrene

Novabiochem®

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About This Item

UNSPSC Code:
13111023

Quality Level

product line

Novabiochem®

form

beads

reaction suitability

reaction type: solution phase peptide synthesis
reactivity: alcohol reactive

manufacturer/tradename

Novabiochem®

application(s)

peptide synthesis

storage temp.

2-8°C

General description

This polymer-bound version of IBX cleanly converts primary and secondary alcohols to the corresponding aldehydes and ketones [1,2]. It is particularly useful for the synthesis of peptide aldehydes as it oxidises peptide alcohols efficiently and spent resin can be simply removed by filtration.

Literature references

[1] G. Sorg, et al. (2001) Angew. Chem. Int. Ed., 40, 4395.
[2] G. Sorg, et al. (2005) J. Pept. Sci.,11, 147.

Application

  • 2-Iodoxybenzoic Acid: An Oxidant for Functional Group Transformations: This study discusses the use of IBX for various organic transformations, including the oxidation of silyl enol ethers and the preparation of polystyrene supported periodinane reagent. (Nair, 2020).

Linkage

Replaces: 01-64-0445

Analysis Note

Color (visual): white to yellow to beige
Appearance of substance (visual): beads
Loading (determined by elemental analysis of iodine): 0.90 - 1.50 mmol/g
Oxidation of Cinnamyl alcohol to Cinnamaldehyde (2 eq. IBX PS): ≥ 90 %
Swelling Volume (in DMF): lot specific result
The polymer matrix is copoly (styrene - 1% DVB) 200 -400 mesh.

Legal Information

Novabiochem is a registered trademark of Merck KGaA, Darmstadt, Germany

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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