1.02403

Potassium dichromate

volumetric standard, secondary reference material for redox titration, traceable to NIST SRM Certipur^® Reag. USP

• Synonym(s): Potassium dichromate, Potassium bichromate, Potassium pyrochromate
• Empirical Formula (Hill Notation): Cr₂K₂O₇
• CAS Number: 7778-50-9
• Molecular Weight: 294.18
• MDL number: MFCD00011367
• UNSPSC Code: 41116107
• EC Index Number: 231-906-6

Properties

• Agency: ISO 17025; reag. USP
• Quality Level: 300
• form: solid
• potency: 90.5 mg/kg LD₅₀, oral (Rat); 1170 mg/kg LD₅₀, skin (Rat)
• technique(s): titration: suitable
• pH: 3.6 (100 g/L in H₂O)
• bp: >500 °C/1013 hPa
• mp: 398 °C
• density: 2.7 g/cm³ at 20 °C
• bulk density: 1250 kg/m³
• storage temp.: 15-25°C
• InChI: 1S/2Cr.2K.7O/q;;2*+1;;;;;;2*-1
• InChI key: KMUONIBRACKNSN-UHFFFAOYSA-N

Description

General description

Potassium dichromate is a volumetric standard manufactured under stringent conditions and measured with the highest possible precision. Its mass fraction is determined by potentiometric titration, and it is qualified in a DIN EN ISO/IEC 17025 accredited laboratory.

Please visit ISO certificates and Site Quality Self-Assessments to access the current certificates of accreditation.

Download your certificate at http://www.sigma-aldrich.com to view certified values, including uncertainty and expiry date.

Application

It finds its use as a certified reference material (CRM) for the standardization of volumetric solutions in redox titrations, according to USP and Ph. Eur.

Features and Benefits

• Available as a solid in a secure glass bottle to ensure its stability for the entire shelf life until opened.
• Certified reference material according to ISO 17034
• High-purity material traceable to NIST SRMs
• Qualified in a DIN EN ISO/IEC 17025 accredited laboratory
• In accordance with the chapter reagents of USP and Ph. Eur
• High-quality offering accurate titer determinations
• Accompanied by a certificate of analysis (CoA)

Packaging

SKU-pack size numbers ending with a "3" are SmartChemicals with an RFID tag on the label for seamless data transfer to the instrument, e.g. xxxxxx1003 or xxxxxxx 4003. More information on www.sigmaaldrich.com/SmartChemicals

Legal Information

CERTIPUR is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS03,GHS05,GHS06,GHS08,GHS09
• Signal Word: Danger
• Hazard Statements: H272 - H301 - H312 - H314 - H330 - H334 - H335 - H340 - H350 - H360FD - H372 - H410
• Precautionary Statements: P210 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Muta. 1B - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Corr. 1B - STOT RE 1 Inhalation - STOT SE 3
• Target Organs: Cardio-vascular system, Respiratory system
• Storage Class Code: 5.1B - Oxidizing hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable