T511609

(S)-TCYP

Aldrich^CPR

• Empirical Formula (Hill Notation): C₆₈H₈₁O₄P
• Molecular Weight: 993.34
• UNSPSC Code: 12161600

Properties

• reaction suitability: reagent type: ligand
• refractive index: n/D
• functional group: phosphine
• SMILES string: OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)C6CCCCC6)C7CCCCC7

Description

General description

(S)-TCYP is a chiral phosphoric acid catalyst that is commonly used in chemical synthesis. It has been found to be particularly effective in promoting enantioselective reactions. The sterically demanding triscyclohexylbenzene at the 3 and 3′ positions of (S)-TCYP contribute significant steric influence and ressult in its to its high levels of enantioselectivity.

Application

(S)-TCYP has been used in asymmetric aza-ene-type reactions, catalyzing the formation of C-C bonds with high levels of diastereoselectivity

Other Notes

Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable