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Key Documents

936162

Sigma-Aldrich

RUMeIPr*

≥95%

Synonym(s):

2-(2,6-Dibenzhydryl-4-methylphenyl)-5-(dimethylamino)-2H-imidazo[1,5-a]pyridin-4-ium chloride

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About This Item

Empirical Formula (Hill Notation):
C42H38ClN3
CAS Number:
Molecular Weight:
620.22
UNSPSC Code:
12161600

Quality Level

Assay

≥95%

form

powder

SMILES string

CN(C)C1=CC=CC2=CN(C3=C(C(C4=CC=CC=C4)C5=CC=CC=C5)C=C(C)C=C3C(C6=CC=CC=C6)C7=CC=CC=C7)C=[N+]21.[Cl-]

Application

RUMeIPr* is a NHC ligand developed by the Szostak Group. This NHC analogue of the priveledged DalPhos scaffold has been used in the following reactions: Au-catalyzed C-C coupling, Au-catalyzed C-N coupling, and Au-catalyzed hydroamination of internal alkynes.

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