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797286

Sigma-Aldrich

2,5-Bis[4-(azidomethyl)phenyl]-1,1-dimethyl-3,4-diphenyl-1H-silole

96%

Synonym(s):

1,1-Dimethyl-2,5-bis[4-(azidomethyl)phenyl]-3,4-diphenylsilole, 2,5-Bis[4-(azidomethyl)phenyl]-1,1-dimethyl-3,4-diphenylsilacyclopenta-2,4-diene, Silole-N3

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About This Item

Empirical Formula (Hill Notation):
C32H28N6Si
CAS Number:
1380491-43-9
Molecular Weight:
524.69
UNSPSC Code:
12352103
PubChem Substance ID:
329768581
NACRES:
NA.23

Assay

96%

form

solid

SMILES string

C[Si]1(C)C(C2=CC=C(CN=[N+]=[N-])C=C2)=C(C3=CC=CC=C3)C(C4=CC=CC=C4)=C1C5=CC=C(CN=[N+]=[N-])C=C5

InChI

1S/C32H28N6Si/c1-39(2)31(27-17-13-23(14-18-27)21-35-37-33)29(25-9-5-3-6-10-25)30(26-11-7-4-8-12-26)32(39)28-19-15-24(16-20-28)22-36-38-34/h3-20H,21-22H2,1-2H3

InChI key

ZMHVJCSUTIHLNO-UHFFFAOYSA-N

General description

Silole is an represents a species of efficient emitter. A variety of applications can be developed through functionalization of silole. Taking advantage of the azide-alkyne click reaction, silole can be easily tailored to construct different materials.

Application

Silole-N3 is a "Clickable" aggregation-induced emission (AIE) material for use in circularly polarised luminescence (CPL).

Certificates of Analysis (COA)

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What makes efficient circularly polarised luminescence in the condensed phase: aggregation-induced circular dichroism and light emission
Jianzhao Liu, Huimin Su, Luming Meng, Yihua Zhao, Chunmei Deng, Jason C. Y. Ng, et al
Chemical Science, 3, 2737-2747 (2013)

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