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692441

Sigma-Aldrich

(R)-[(RuCl(T-BINAP))2(μ-Cl)3[NH2Me2]

Synonym(s):

Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2′-bis(di-p-tolylphosphino)-1,1′-binaphthyl]diruthenate(II)

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About This Item

Linear Formula:
(CH3)2NH2+[C96H80Cl5P4Ru2]−
CAS Number:
749935-02-2
Molecular Weight:
1783.05
MDL number:
MFCD09753034
UNSPSC Code:
12352005
PubChem Substance ID:
329761498
NACRES:
NA.22

form

powder

storage temp.

2-8°C

SMILES string

Cl.[Cl-].CNC.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2.Cc3ccc(cc3)P(c4ccc(C)cc4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9ccc(C)cc9)c%10ccc(C)cc%10.Cc%11ccc(cc%11)P(c%12ccc(C)cc%12)c%13ccc%14ccccc%14c%13-c%15c(ccc%16ccccc%15%16)P(c%17ccc(C)cc%17)c%18ccc(C)cc%18

InChI

1S/2C48H40P2.C2H7N.2ClH.3Cl.2Ru/c2*1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;1-3-2;;;;;;;/h2*5-32H,1-4H3;3H,1-2H3;2*1H;;;;;/q;;;;;3*+1;2*-1/p-1

InChI key

QGBBTZBFEYSGDQ-UHFFFAOYSA-M

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for research purposes only.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Articles

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

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