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668192

Sigma-Aldrich

(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4- a′]dinaphthalen-4-yl)dimethylamine

97%

Synonym(s):

(S)-MonoPhos®

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About This Item

Empirical Formula (Hill Notation):
C22H18NO2P
CAS Number:
185449-80-3
Molecular Weight:
359.36
MDL number:
MFCD03426988
UNSPSC Code:
12352005
PubChem Substance ID:
24884967
NACRES:
NA.22

Quality Level

100

Assay

97%

form

solid

mp

190 °C (dec.)

InChI

1S/C22H18NO2P/c1-23(2)26-24-19-13-11-15-7-3-5-9-17(15)21(19)22-18-10-6-4-8-16(18)12-14-20(22)25-26/h3-14H,1-2H3

InChI key

QCHAVHXSBZARBO-UHFFFAOYSA-N

Related Categories

Application

DSM MonoPhos Family of Highly Efficient Privileged Ligands

Legal Information

Sold under license from DSM for research purposes only.
MonoPhos is a registered trademark of DSM IP Assets B.V.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Articles

DSM MonoPhos Family

A diverse array of these chiral, monodentate phosphoramidites based on the privileged BINOL platform. The MonoPhos™ family has exhibited high levels of enantiocontrol in synthetic transformations ranging from metal-catalyzed asymmetric 1,4-additions of organometallic reagents to allylic alkylations to desymmetrization of meso-cycloalkene oxides.

DSM MonoPhos™ Ligands

In collaboration with DSM, we are pleased to offer a range of MonoPhos™ ligands for the research market.† Feringa and co-workers have invented a diverse array of these chiral, monodentate phosphoramidites based on the privileged BINOL platform.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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