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550787

Sigma-Aldrich

Vanadyl acetylacetonate

98%

Synonym(s):

VO(acac)2, Vanadium(IV)-oxy acetylacetonate

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About This Item

Linear Formula:
OV(C5H7O2)2
CAS Number:
3153-26-2
Molecular Weight:
265.16
Beilstein:
4138236
EC Number:
221-590-8
MDL number:
MFCD00000032
UNSPSC Code:
12352103
PubChem Substance ID:
24879146
NACRES:
NA.23

Assay

98%

form

solid

mp

235 °C (dec.) (lit.)

SMILES string

CC(=O)\C=C(\C)O[V](=O)O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.O.V/c2*1-4(6)3-5(2)7;;/h2*3,6H,1-2H3;;/q;;;+2/p-2/b2*4-3-;;

InChI key

JFHJZWAQYMGNBE-SUKNRPLKSA-L

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Application

Vanadyl acetylacetonate may be used as a precursor for the preparation of vanadium dioxide thin films for applications in “intelligent” window coating and data storage.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H315,H319,H335

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKBW9889V
MKBW9874V
MKBW1344V
MKBW1340V
MKBS2189V

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Xinjian Shi et al.
Physical chemistry chemical physics : PCCP, 18(13), 9255-9261 (2016-03-16)
WO3-BiVO4 n-n heterostructures have demonstrated remarkable performance in photoelectrochemical water splitting due to the synergistic effect between the individual components. Although the enhanced functional capabilities of this system have been widely reported, in-depth mechanistic studies explaining the carrier dynamics of
Tengfei Li et al.
Nature communications, 8(1), 390-390 (2017-09-01)
There is a global effort to convert sunlight into fuels by photoelectrochemically splitting water to form hydrogen fuels, but the dioxygen byproduct bears little economic value. This raises the important question of whether higher value commodities can be produced instead
Doped and un-doped vanadium dioxide thin films prepared by atmospheric pressure chemical vapour deposition from vanadyl acetylacetonate and tungsten hexachloride: the effects of thickness and crystallographic orientation on thermochromic properties.
Binions R,et al.
Journal of Materials Chemistry, 17, 4652-4660 (2007)
On the effects of electric fields in aerosol assisted chemical vapour deposition reactions of vanadyl acetylacetonate solutions in ethanol
Warwick MEA and Binions R
Journal of Nanoscience and Nanotechnology, 11(9), 8126-8131 (2011)
Szymon Kowalski et al.
International journal of molecular sciences, 20(2) (2019-01-13)
Pancreatic cancer is characterized by one of the lowest five-year survival rates. In search for new treatments, some studies explored several metal complexes as potential anticancer drugs. Therefore, we investigated three newly synthesized oxidovanadium(IV) complexes with 2-methylnitrilotriacetate (bcma3-), N-(2-carbamoylethyl)iminodiacetate (ceida3-)
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