Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

361763

Sigma-Aldrich

2,3:5,6-Di-O-isopropylidene-α-D-mannofuranose

97%

Synonym(s):

D-Mannose diacetonide

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C12H20O6
CAS Number:
14131-84-1
Molecular Weight:
260.28
Beilstein:
84382
MDL number:
MFCD00134206
UNSPSC Code:
12352201
PubChem Substance ID:
24862256
NACRES:
NA.22

Assay

97%

form

solid

optical activity

[α]20/D +23°, c = 1 in acetone

mp

125-126 °C (dec.) (lit.)

SMILES string

CC1(C)OC[C@@H](O1)[C@H]2OC(O)[C@@H]3OC(C)(C)O[C@@H]23

InChI

1S/C12H20O6/c1-11(2)14-5-6(16-11)7-8-9(10(13)15-7)18-12(3,4)17-8/h6-10,13H,5H2,1-4H3/t6?,7-,8+,9?,10?/m1/s1

InChI key

JWWCLCNPTZHVLF-RGJLLFKYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

Application

Protected mannose intermediate used in the syntheses of ovalicin and of the sugar core of hikizimycin.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCF0611
MKBW5300V
MKBP4367V
MKBN3366V
MKBJ9276V

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Furstner, A. et al.
Chemistry (Weinheim An Der Bergstrasse, Germany), 12, 76-76 (2006)
Shunya Takahashi et al.
The Journal of organic chemistry, 70(24), 10162-10165 (2005-11-19)
[reaction: see text] A new synthesis of epoxyketone 22 is described that is a key intermediate in Barton's synthesis of ovalicin (2), a powerful anti-angiogenetic inhibitor. The key process for the construction of 22 was ring-closing metathesis of olefins 11

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service