288101

(Acetylacetonato)dicarbonylrhodium(I)

98%

• Synonym(s): Dicarbonyl-acetylacetonato-rhodium(I), Dicarbonylrhodium(I) 2,4-pentanedionate, Rh(CO)₂acac, Rhodium(I) dicarbonyl acetylacetonate
• Linear Formula: Rh(CO)₂(C₅H₇O₂)
• CAS Number: 14874-82-9
• Molecular Weight: 258.03
• EC Number: 238-947-9
• MDL number: MFCD00009884
• UNSPSC Code: 12352103
• PubChem Substance ID: 24857317
• NACRES: NA.23

Properties

• Assay: 98%
• form: solid
• reaction suitability: reagent type: catalyst
• mp: 154-156 °C (lit.)
• SMILES string: [C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Rh]
• InChI: 1S/C5H8O2.2CO.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;
• InChI key: BZCAWKOPWNIDOC-FGSKAQBVSA-M

Description

Application

Employed in in situ formation of a fluorous-soluble hydroformylation catalyst of interest in molecular engineering.

Safety Information

• Pictograms: GHS02,GHS06,GHS09
• Signal Word: Danger
• Hazard Statements: H228,H301,H317,H319,H411
• Precautionary Statements: P210 - P273 - P280 - P301 + P310 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Sol. 1 - Skin Sens. 1
• Supplementary Hazards: EUH044
• Storage Class Code: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves