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B85919

Sigma-Aldrich

(±)-2-Butanol

ReagentPlus®, ≥99%

Sinónimos:

sec-Butyl alcohol

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About This Item

Fórmula lineal:
CH3CH2CH(OH)CH3
Número de CAS:
78-92-2
Peso molecular:
74.12
Beilstein/REAXYS Number:
773649
EC Number:
201-158-5
MDL number:
MFCD00004569
UNSPSC Code:
12352001
PubChem Substance ID:
329773311
NACRES:
NA.21
assay:
≥99%
bp:
98 °C (lit.)
vapor pressure:
12.5 mmHg ( 20 °C)

vapor density

2.6 (vs air)

Quality Level

100

vapor pressure

12.5 mmHg ( 20 °C)

product line

ReagentPlus®

assay

≥99%

form

liquid

autoignition temp.

761 °F

expl. lim.

9.8 %

IVD

for in vitro diagnostic use

refractive index

n20/D 1.397 (lit.)

bp

98 °C (lit.)

mp

−115 °C (lit.)

density

0.808 g/mL at 25 °C (lit.)

SMILES string

CCC(C)O

InChI

1S/C4H10O/c1-3-4(2)5/h4-5H,3H2,1-2H3

InChI key

BTANRVKWQNVYAZ-UHFFFAOYSA-N

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General description

2-Butanol is secondary alcohol mainly used as a solvent in organic synthesis. 2-butanol readily converts into 2-butanone (methyl ethyl ketone, MEK), which is used as a solvent in the industrial sector and many domestic cleaning products. It is an intermediate in devulcanizing rubber and the production of alkyl ester for use as biodiesel fuel.

Application

2-Butanol is used:
  • As a precursor to produce 2-butanone in presence of KMnO4 oxidant and CPC (N-cetylpyridinium chloride) micellar catalyst.
  • In the production of CH3NH3PbI3 perovskite films.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

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pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3

target_organs

Central nervous system, Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

80.6 °F - closed cup

flash_point_c

27 °C - closed cup

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Certificados de análisis (COA)

Lot/Batch Number
STBK6310
SHBP1384
SHBP0172
SHBN9400
SHBN7892

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Flaminia Rondino et al.
Physical chemistry chemical physics : PCCP, 13(3), 818-824 (2010-12-07)
Diastereomeric adducts between (S)-1-(4-fluorophenyl)-ethanol and R and S 2-butanol, formed by supersonic expansion, have been investigated by means of a combination of mass selected resonant two-photon ionization-spectroscopy and infrared depletion spectroscopy. Chiral recognition is evidenced by the specific spectroscopic signatures
Feng Gao et al.
Journal of the American Chemical Society, 129(49), 15240-15249 (2007-11-16)
The enantioselective chemisorption of R- and S-propylene oxide has been measured either on clean Pd(111) that has been exposed to S-2-butanol at various temperatures to vary the proportion of 2-butanol and 2-butoxide species or by adsorbing S-2-butanol on oxygen-covered Pd(111)
Timothy E Morey et al.
AIDS and behavior, 17(1), 298-306 (2012-09-25)
A breath-based adherence system to document ingestion of oral medications (e.g., HAART) was investigated. Specifically, the food additive 2-butanol, which can be easily packaged with a drug, is converted via alcohol dehydrogenase to the volatile metabolite 2-butanone that rapidly appears
R A Rosenberg et al.
Physical review letters, 101(17), 178301-178301 (2008-11-13)
We demonstrate for the first time that low-energy spin-polarized secondary electrons, produced by irradiation of a magnetic substrate, can induce chiral-selective chemistry. Our approach was to perform detailed measurements of the reaction rate for x-ray induced, secondary electron photolysis of
Hirofumi Sonoda et al.
The Journal of biological chemistry, 282(47), 34085-34092 (2007-09-28)
Although organelles such as the endoplasmic reticulum and Golgi apparatus are highly compartmentalized, these organelles are interconnected through a network of vesicular trafficking. The marine sponge metabolite ilimaquinone (IQ) is known to induce Golgi membrane fragmentation and is widely used
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