431354

Ammonium thiocyanate

99.99% trace metals basis

• Sinónimos: Ammonium rhodanide
• Fórmula lineal: NH₄SCN
• Número de CAS: 1762-95-4
• Peso molecular: 76.12
• Beilstein/REAXYS Number: 3595135
• EC Number: 217-175-6
• MDL number: MFCD00011428
• UNSPSC Code: 12352300
• eCl@ss: 38060604
• PubChem Substance ID: 329756312
• NACRES: NA.55

Propiedades

• grade: for inorganic trace analysis
• Quality Level: 100
• assay: 99.99% trace metals basis
• form: crystals
• impurities: ≤0.004 meq/g I₂ consumers; ≤0.005% insolubles
• ign. residue: ≤0.025%
• pH: 4.5-6.0
• mp: 152-154 °C (lit.)
• solubility: water: 76.1 g/L at 20 °C
• anion traces: chloride (Cl^-): ≤0.005%; sulfate (SO₄^2-): ≤0.005%
• cation traces: Fe: ≤3 ppm; heavy metals: ≤5 ppm
• SMILES string: N.SC#N
• InChI: 1S/CHNS.H3N/c2-1-3;/h3H;1H3
• InChI key: SOIFLUNRINLCBN-UHFFFAOYSA-N

Descripción

General description

Ammonium thiocyanate is an ammonium salt commonly used for thiocyanation reaction of organic compounds.

Application

Ammonium thiocyanate (ATC) may be used the synthesis of the following:

• Graphitic carbon nitride.
• Three-dimensional nitrogen and sulfur co-doped graphene frameworks (N/S-GFs).
• Substituted 2-aminothiazole derivatives by reacting with α-halo ketone carbonyls in the presence of N-methylimidazole.
• Thiiranes from corresponding oxiranes in the presence of LiBF₄.
• 1,2,4-triazole-3-thiones by a multi-component reaction with benzohydrazide acid and acid chloride in the absence of solvent.

Applied in the formation of novel two-dimensional Cd-SCN coordination solids with unusual and tailorable, checkerboard- or herringbone-patterned structures these structures are important steps toward technologically useful materials.

Features and Benefits

Meets ACS reagent specifications.

Información de seguridad

• pictograms: GHS05,GHS07
• signalword: Danger
• hcodes: H302 + H312 + H332,H318,H412
• pcodes: P273 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1
• supp_hazards: EUH032
• Storage Class: 13 - Non Combustible Solids
• wgk_germany: WGK 1
• flash_point_f: Not applicable
• flash_point_c: Not applicable