186325
Methyl acetate
ReagentPlus®, 99%
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About This Item
Fórmula lineal:
CH3COOCH3
Número de CAS:
Peso molecular:
74.08
Beilstein/REAXYS Number:
1736662
EC Number:
MDL number:
UNSPSC Code:
12352108
PubChem Substance ID:
NACRES:
NA.21
assay:
99%
bp:
57-58 °C (lit.)
vapor pressure:
165 mmHg ( 20 °C)
Productos recomendados
vapor density
2.55 (vs air)
Quality Level
vapor pressure
165 mmHg ( 20 °C)
product line
ReagentPlus®
assay
99%
form
liquid
autoignition temp.
936 °F
expl. lim.
16 %
refractive index
n20/D 1.361 (lit.)
bp
57-58 °C (lit.)
mp
−98 °C (lit.)
density
0.934 g/mL at 25 °C
SMILES string
COC(C)=O
InChI
1S/C3H6O2/c1-3(4)5-2/h1-2H3
InChI key
KXKVLQRXCPHEJC-UHFFFAOYSA-N
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General description
Its IR spectra in the vapor phase and in solution form (in CS2 and CCl4) have been reported. It can be synthesized from dimethyl ether via carbonylation in the presence of halide-free catalysts based on zeolites. It has also been reported to be formed during the synthesis of poly(vinyl) alcohol (PVA). It undergoes transesterification reaction with n-octanol in the presence of Amberlyst 15 catalyst to afford octyl acetate and methanol.
Methyl acetate is an aliphatic ester that can be prepared via carbonylation of dimethyl ether over zeolites. MA is formed as a by-product during the preparation of polyvinyl alcohol from acetic acid and methanol.
Application
Methyl acetate may be used for the preparation of fatty acid methyl esters and triacetin from rapeseed oil via non-catalytic trans-esterification reaction under super-critical conditions.
Methyl acetate may be used in the following:
- As acyl acceptor in the preparation of biodiesel.
- Synthesis of ethanol.
- Preparation of n-butyl acetate, via transesterification reaction with n-butanol in the presence of acidic catalysts.
- acetic anhydride
- methyl acrylate
- vinyl acetate
- ethyl amide
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Central nervous system
supp_hazards
Storage Class
3 - Flammable liquids
wgk_germany
WGK 1
flash_point_f
8.6 °F - closed cup
flash_point_c
-13 °C - closed cup
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Los clientes también vieron
Kinetics of transesterification of methyl acetate and n-octanol catalyzed by cation exchange resins.
Liu Y, et al.
Korean Journal of Chemical Engineering, 30(5), 1039-1042 (2013)
Catalysts, Kinetics, and Reactive Distillation for Methyl Acetate Synthesis.
Zuo C, et al.
Industrial & Engineering Chemistry Research, 53(26), 10540-10548 (2014)
A new process for catalyst-free production of biodiesel using supercritical methyl acetate.
Saka S and Isayama Y.
Fuel: The Science and Technology of Fuel and Energy, 88(7), 1307-1313 (2009)
Selective carbonylation of dimethyl ether to methyl acetate catalyzed by acidic zeolites.
Patricia Cheung et al.
Angewandte Chemie (International ed. in English), 45(10), 1617-1620 (2006-01-31)
Synthesis of ethanol from methanol and syngas through an indirect route containing methanol dehydrogenation, DME carbonylation, and methyl acetate hydrogenolysis.
Liu Y, et al.
Fuel Processing Technology, 110, 206-213 (2013)
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