270970

Pyridine

anhydrous, 99.8%

• Fórmula empírica (notación de Hill): C₅H₅N
• Número de CAS: 110-86-1
• Peso molecular: 79.10
• Beilstein/REAXYS Number: 103233
• EC Number: 203-809-9
• MDL number: MFCD00011732
• UNSPSC Code: 12352005
• PubChem Substance ID: 57648214
• NACRES: NA.21

Propiedades

• grade: anhydrous
• Quality Level: 200; 300
• vapor density: 2.72 (vs air)
• vapor pressure: 10 mmHg ( 13.2 °C); 20 mmHg ( 25 °C)
• assay: 99.8%
• form: liquid
• autoignition temp.: 899 °F
• expl. lim.: 12.4 %
• impurities: <0.003% water; <0.005% water (100 mL pkg)
• evapn. residue: <0.0005%
• color: colorless
• refractive index: n20/D 1.509 (lit.)
• pH: ~8.81 (20 °C)
• bp: 115 °C (lit.)
• mp: −42 °C (lit.)
• density: 0.978 g/mL at 25 °C (lit.)
• SMILES string: C1=CN=CC=C1
• InChI: 1S/C5H5N/c1-2-4-6-5-3-1/h1-5H
• InChI key: JUJWROOIHBZHMG-UHFFFAOYSA-N

Descripción

General description

Pyridine is a basic N-heterocyclic compound. It acts as nitrogen donor ligand and forms many metal-pyridine complexes. Its complexes having tetrahedral and octahedral geometries can be differentiated by infra-red spectral investigations.

Application

Pyridine (py) may be used in the preparation of vanadium oxide nanoparticles and iron benzenedicarboxylates, Fe(OH)(BDC)(py)_0.85 (BDC = 1,4-benzenedicarboxylate, py = pyridine). It may be employed as catalyst in Knoevenagel condensation reaction.

Pyridine may be used as a base for the conversion of:

• Alkyltrichlorosilanes to trimethoxyalkylsilanes, which are used as precursors for preparing alkylsilicates.
• 1-Indanone to 1-indanone oxime, which can undergo reductive ring-expansion to form tetrahydroquinoline.

It may also be used to catalyze the borylation reaction of haloarenes to form arylboronates without using transition metal catalysts.

Packaging

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Información de seguridad

• pictograms: GHS02,GHS07
• signalword: Danger
• hcodes: H225 - H302 + H312 + H332 - H315 - H319
• pcodes: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 2
• flash_point_f: 68.0 °F - closed cup
• flash_point_c: 20 °C - closed cup
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter