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194832

Sigma-Aldrich

Dithizone

ACS reagent, ≥85.0%

Sinónimos:

Diphenylthiocarbazone

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About This Item

Fórmula lineal:
C6H5NHNHCSN=NC6H5
Número de CAS:
60-10-6
Peso molecular:
256.33
Beilstein/REAXYS Number:
748838
EC Number:
200-454-1
MDL number:
MFCD00003025
UNSPSC Code:
12352100
PubChem Substance ID:
24851336

grade

ACS reagent

assay

≥85.0%

ign. residue

≤0.3%

mp

168 °C (dec.) (lit.)

cation traces

heavy metals: ≤0.002%

absorbance ratio

A ≥1.55

SMILES string

S=C(NNc1ccccc1)\N=N\c2ccccc2

InChI

1S/C13H12N4S/c18-13(16-14-11-7-3-1-4-8-11)17-15-12-9-5-2-6-10-12/h1-10,14H,(H,16,18)/b17-15+

InChI key

UOFGSWVZMUXXIY-BMRADRMJSA-N

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General description

Dithizone (Diphenylthiocarbazone) is used as chelating agent for zinc. It is widely used for the liquid-liquid and solid phase extraction of various metals since it forms stable complexes with the metals.

Application

Dithizone (Diphenylthiocarbazone) may be used in the following studies:
  • In the cloud point preconcentration step, before the trace level quantification of silver by flame atomic absorption spectrometry.
  • Preparation of hexadecyltrimethyl ammonium bromide (CTAB) capped gold nanoparticles (AuNPs). This reagent was useful for the colorimetric detection of heavy metal ions.
  • As a zinc chelating ligand for the extraction of zinc in bovine serum.
Dithizone has been used in the preparation of dithizone stain solution for pancreatic islet cells.
Indicator for metals.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificados de análisis (COA)

Lot/Batch Number
BCBV6451
BCBV3000
BCBT4987
BCBR6911V
BCBQ6756V

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Analytica Chimica Acta, 57, 393-393 (1971)
Sonic hedgehog inhibition induces mouse embryonic stem cells to differentiate toward definitive endoderm.
Ghanbari A, et al.
Indian Journal of Experimental Biology, 51, 201-207 (2013)
Yumin Leng et al.
Langmuir : the ACS journal of surfaces and colloids, 29(25), 7591-7599 (2013-06-04)
A new kind of analytical reagent, hexadecyl trimethyl ammonium bromide (CTAB), and dithizone product-modified gold nanoparticle dispersion, is developed for colorimetric response to 10 types of heavy metal ions (M(n+)), including Cr(VI), Cr(3+), Mn(2+), Co(2+), Ni(2+), Cu(2+), Zn(2+), Cd(2+), Hg(2+)
Wei Yue et al.
Electroanalysis, 25(10), 2259-2267 (2014-01-18)
Metal catalyst free carbon nanotube (MCFCNT) whiskers were first used as an electrode modification material on a gold electrode surface for zinc voltammetric measurements. A composite film of Nafion and MCFCNT whiskers was applied to a gold electrode surface to
Selective cloud point extraction and preconcentration of trace amounts of silver as a dithizone complex prior to flame atomic absorption spectrometric determination.
Manzoori JL and Karim-Nezhad G.
Analytica Chimica Acta, 484(2), 155-161 (2003)
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