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Merck
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Documentos

28-1310

Sigma-Aldrich

Nitrato de plata

JIS special grade, ≥99.8%

Sinónimos:

Sal de plata (I) del ácido nítrico

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About This Item

Fórmula lineal:
AgNO3
Número de CAS:
7761-88-8
Peso molecular:
169.87
MDL number:
MFCD00003414
UNSPSC Code:
12352302
PubChem Substance ID:
329753055

grade

JIS special grade

vapor density

5.8 (vs air)

assay

≥99.8%

form

solid

availability

available only in Japan

mp

212 °C (dec.) (lit.)

storage temp.

15-25°C

SMILES string

[O-][N+]([O-])=O.[Ag+]

InChI

1S/Ag.NO3/c;2-1(3)4/q+1;-1

InChI key

SQGYOTSLMSWVJD-UHFFFAOYSA-N

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General description

Silver nitrate is a versatile reagent that can be prepared by reacting silver with nitric acid. It is used in various fields such as organic synthesis, photography, silver paints, dyes, chemical analysis, gravimetric analysis, and pharmaceutical preparations.

Application

Silver nitrate can be used as a catalyst in the:
  • [3+2]-Cycloaddition of Ͱ-diazocarbonyl compounds with arenediazonium salts to synthesize 2,5-disubstituted tetrazoles.
  • Oxidation of aromatic, aliphatic, and conjugated aldehydes to corresponding carboxylic acids in the presence of H2O2 as an oxidant.
  • Lactamization of methyl Ͱ,Ͱ-disubstituted Ͱ-isocyanoacetates with primary amines to synthesize 3,5,5-trisubstituted imidazolones.

It can also be used as a:
  • Reagent to synthesize bisazetanes from the oxidation of azetidine.

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Repr. 1B - Skin Corr. 1A

Storage Class

5.1B - Oxidizing hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Liming Wang et al.
ACS nano, 9(6), 6532-6547 (2015-05-23)
To predict potential medical value or toxicity of nanoparticles (NPs), it is necessary to understand the chemical transformation during intracellular processes of NPs. However, it is a grand challenge to capture a high-resolution image of metallic NPs in a single
Irina Blinova et al.
Environmental science and pollution research international, 20(5), 3456-3463 (2012-11-13)
Although silver nanoparticles (NPs) are increasingly used in various consumer products and produced in industrial scale, information on harmful effects of nanosilver to environmentally relevant organisms is still scarce. This paper studies the adverse effects of silver NPs to two
Tao Xu et al.
Organic letters, 14(21), 5416-5419 (2012-10-24)
A silver-catalyzed intramolecular oxidative aminofluorination of alkynes has been developed by using NFSI as a fluorinating reagent. This reaction represents an efficient method for the synthesis of various 4-fluoroisoquinolines and 4-fluoropyrrolo[α]isoquinolines.
Benjamin P Colman et al.
PloS one, 8(2), e57189-e57189 (2013-03-08)
A large fraction of engineered nanomaterials in consumer and commercial products will reach natural ecosystems. To date, research on the biological impacts of environmental nanomaterial exposures has largely focused on high-concentration exposures in mechanistic lab studies with single strains of
Lara Settimio et al.
Environmental pollution (Barking, Essex : 1987), 191, 151-157 (2014-05-20)
The fate and lability of added soluble Ag in soils over time was examined by measurement of labile metal (E-value) by isotopic dilution using the (110m)Ag radioactive isotope and the solid-phase speciation of Ag by X-ray absorption near edge structure
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