8.03945

Iron(III) chloride

anhydrous for synthesis

• Sinónimos: Iron(III) chloride, Ferric chloride, Iron trichloride
• Fórmula empírica (notación de Hill): Cl₃Fe
• Número de CAS: 7705-08-0
• Peso molecular: 162.20
• MDL number: MFCD00011005
• UNSPSC Code: 12352302
• EC Index Number: 231-729-4
• NACRES: NA.22

Propiedades

• vapor pressure: 1 hPa ( 20 °C)
• Quality Level: 200
• form: powder
• potency: 316 mg/kg LD₅₀, oral (Rat)
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• pH: 1 (20 °C, 200 g/L in H₂O)
• mp: 306 °C (decomposition)
• solubility: 920 g/L (Hydrolysis)
• density: 2.89 g/cm³ at 25 °C
• bulk density: 1000 kg/m³
• greener alternative category: , Aligned
• storage temp.: 2-30°C
• InChI: 1S/3ClH.Fe/h3*1H;/q;;;+3/p-3
• InChI key: RBTARNINKXHZNM-UHFFFAOYSA-K

Descripción

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Iron(III) chloride (FeCl₃) can be used as a catalyst:

• For the oxidation of glucose to gluconic acid in water.
• To synthesize 2-iodo substituted benzo[b]thiophenes by iodocyclization of 2-alkynylthioanisoles in the presence of sodium iodide and ethanol as a solvent.
• In the glycosylation sugars in the presence of allyl and alkynyl alcohols to synthesize corresponding glycosides.
• To prepare 1,2-trans glycosyl azides by azido glycosylation of glycosyl β-peracetates.

Analysis Note

Assay (iodometric): ≥ 98.0 %
Identity (Fe): passes test
Identity (Cl): passes test

Información de seguridad

• pictograms: GHS05,GHS07
• signalword: Danger
• hcodes: H290,H302,H315,H317,H318
• pcodes: P234 - P261 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2 - Skin Sens. 1
• Storage Class: 8B - Non-combustible corrosive hazardous materials
• wgk_germany: WGK 1
• flash_point_f: Not applicable
• flash_point_c: Not applicable