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Merck

P35405

Sigma-Aldrich

Diphenyl sulfoxide

96%

Sinónimos:

Phenyl sulfoxide

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About This Item

Fórmula lineal:
(C6H5)2SO
Número de CAS:
Peso molecular:
202.27
Beilstein/REAXYS Number:
1908444
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

96%

form

crystals

bp

206-208 °C/13 mmHg (lit.)

mp

69-71 °C (lit.)

SMILES string

O=S(c1ccccc1)c2ccccc2

InChI

1S/C12H10OS/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H

InChI key

JJHHIJFTHRNPIK-UHFFFAOYSA-N

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Application

  • Preparation of radiochemicals: Diphenyl sulfoxide plays a role in the synthesis of [(11)C]cyanide from [(11)C]methyl iodide, facilitating rapid and efficient production of radiochemicals for medical imaging applications (Kikuchi et al., 2022).
  • Catalytic oxidation processes: The photocatalytic and catalytic oxidation of diphenyl sulphide to sulfoxide and sulfone was examined, highlighting the effectiveness of hydrogen peroxide and TiO2 polymorphs in optimizing chemical processes (Mikrut et al., 2022).
  • Dielectric properties research: The study on dielectric properties of high organic sulfur coal highlighted the modeling of sulfur compounds, which could include diphenyl sulfoxide, enhancing our understanding of materials science in energy sectors (Cai et al., 2019).

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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S Yoshihara et al.
Archives of biochemistry and biophysics, 249(1), 8-14 (1986-08-15)
To characterize the properties of diphenyl sulfoxide (DPSO) as a new type of electron acceptor for guinea pig liver aldehyde oxidase (AO), we compared the kinetics of the reductions of DPSO and other classical electron acceptors such as O2 and
Wen-xian Li et al.
Guang pu xue yu guang pu fen xi = Guang pu, 22(6), 905-907 (2003-08-14)
(Tb1-x Tmx).L2.(ClO4).2H2O(x = 0.000 to 0.200, L = C6H5SOCH2COO-) have been synthesized. The coordination compounds have been studied by means of composition analysis, molar conductivity, IR, and the condition of coordination have been inferred. In the fluorescent spectra it was
J A Kozlowski et al.
Bioorganic & medicinal chemistry letters, 10(20), 2255-2257 (2000-10-31)
Structure activity studies on [4-(phenylsulfonyl)phenyl]methylpiperazine led to the discovery of 4-cyclohexyl-alpha-[4-[[4-methoxyphenyl(S)-sufinyl]phenyl]-1-pi perazineacetonitrile, 1, an M2 selective muscarinic antagonist. Affinity at the cloned human M2 receptor was 2.7 nM; the M1/M2 selectivity is 40-fold.
Wen-Xian Li et al.
Luminescence : the journal of biological and chemical luminescence, 26(6), 754-761 (2011-05-14)
A novel ternary complex, TbL(5) L'(ClO(4))(3) · 3H(2)O, two binary complexes, TbL(7) (ClO(4))(3) · 3H(2)O and TbL'(3.5) (ClO(4))(3) · 4H(2)O has been synthesized (using diphenyl sulphoxide as the first ligand L, bipyridine as the second ligand L'). Their composition was
Tomofumi Takuwa et al.
Chemical & pharmaceutical bulletin, 53(5), 476-480 (2005-05-03)
A facile one-pot C-benzylation of various sodium enolates derived from methyl malonate, beta-ketoesters, a beta-cyanoester, a beta-cyanosulfone, ketones and a carboxylic ester is reported. Reaction of alkoxydiphenylsulfonium salts formed by treating various benzyl alcohols with diphenyl sulfide bis(trifluoromethanesulfonate) (derived from

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