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Merck
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Key Documents

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N32601

Sigma-Aldrich

Norcamphor

98%

Sinónimos:

2-Norbornanone, Bicyclo[2.2.1]heptan-2-one

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About This Item

Fórmula empírica (notación de Hill):
C7H10O
Número de CAS:
497-38-1
Peso molecular:
110.15
Beilstein/REAXYS Number:
1209657
EC Number:
207-846-1
MDL number:
MFCD00074823
UNSPSC Code:
12352100
PubChem Substance ID:
24897635
NACRES:
NA.22

assay

98%

form

crystals

bp

168-172 °C (lit.)

mp

93-96 °C (lit.)

SMILES string

O=C1C[C@@H]2CC[C@H]1C2

InChI

1S/C7H10O/c8-7-4-5-1-2-6(7)3-5/h5-6H,1-4H2/t5-,6+/m1/s1

InChI key

KPMKEVXVVHNIEY-RITPCOANSA-N

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pictograms

Flame
GHS02

signalword

Danger

hcodes

H228

pcodes

P210

Hazard Classifications

Flam. Sol. 1

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 3

flash_point_f

91.4 °F - closed cup

flash_point_c

33 °C - closed cup

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Bicyclo[2.2.1]hept-2-ene 99%

Sigma-Aldrich

N32407

Bicyclo[2.2.1]hept-2-ene

Lars Goerigk et al.
The journal of physical chemistry. A, 113(4), 767-776 (2008-12-24)
Time-dependent double-hybrid density functional theory is applied to the calculation of the electronic circular dichroism (CD) spectra of molecules. The TD-B2PLYP method is based on vertical excitation energies obtained from its hybrid-GGA part B2LYP in a conventional TD-DFT linear response
Lucyna Balcerzak et al.
Food chemistry, 301, 125283-125283 (2019-08-05)
A small library of 57 low molecular weight oximes was prepared from fragrant aldehydes and ketones, and their olfactory profiles were determined. The most substantive and interesting in terms of the sensory impressions were (+)-isomenthone oxime (fresh, musty, green) and
M D Paulsen et al.
Protein science : a publication of the Protein Society, 2(3), 357-365 (1993-03-01)
Cytochrome P450cam (P450CIA1) catalyzes the hydroxylation of camphor and several substrate analogues such as norcamphor and 1-methyl-norcamphor. Hydroxylation was found experimentally at the 3, 5, and 6 positions of norcamphor, but only at the 5 and 6 positions of 1-methyl-norcamphor.
W M Atkins et al.
Biochemistry, 27(5), 1610-1616 (1988-03-08)
The kinetics of NADH consumption, oxygen uptake, and hydrogen peroxide production have been studied for norcamphor metabolism by cytochrome P-450cam. The kinetic deuterium isotope effects on these processes, with specifically deuteriated norcamphor, are 0.77, 1.22, and 1.16, respectively. Steady-state UV-visible
Sarasij Kumar Upadhyay et al.
The Journal of organic chemistry, 76(5), 1355-1360 (2011-01-22)
The endo/exo product ratio in the reactions of SmI(2) with norcamphor in the presence of various proton donors was determined. The effect of MeOH, EtOH, trifluoroethanol (TFE), ethylene glycol (EG), and water was investigated at various concentrations of these proton
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