939633

Indoline-2-thione

≥-95%

• Sinónimos: 2,3-Dihydro-1H-indole-2-thione
• Fórmula empírica (notación de Hill): C₈H₇NS
• Número de CAS: 496-30-0
• Peso molecular: 149.21
• MDL number: MFCD09971323
• UNSPSC Code: 12352100

Propiedades

• Quality Level: 100
• assay: ≥-95%
• form: powder or crystals
• reaction suitability: reaction type: Photocatalysis
• color: white to yellow
• SMILES string: S=C1NC2=CC=CC=C2C1
• InChI: InChI=1S/C8H7NS/c10-8-5-6-3-1-2-4-7(6)9-8/h1-4H,5H2,(H,9,10)
• InChI key: IGJWTYFTQNHSEK-UHFFFAOYSA-N

Descripción

General description

Indoline-2-thione is a indole thiolate often used in the synthesis of (Indoline-2-S) related products.

Application

Indoline-2-thione is a indole thiolate has been used in:

• The MgI₂-catalyzed nucleophilic ring opening of donor-acceptor cyclopropanes
• The synthesis of indole-fused dihydrothiopyrano scaffolds via [3+3] annulations of donor-acceptor cyclopropanes
• The preparation of 2-carboxylated thieno [2,3- b] indoles

Also used as a catalytic photoreductant in:

• The synthesis of thioethers from aryl chlorides & alcohols

Features and Benefits

1-Methylindoline-2-thione is an affordable indole thiolate that is useful in general synthesis as well as the transition-metal free photocatalytic reduction of a range of strong polar C-F, C-O and C-Cl bonds.

Información de seguridad

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3