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908703

Sigma-Aldrich

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6

≥95%

Sinónimos:

[(4,4′-di-tert-butyl-2,2′-bipyridine)-bis-(5-methyl-2-(5-fluoro-phenyl)-pyridine)-iridium(III)] hexafluorophosphate

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About This Item

Fórmula empírica (notación de Hill):
C42H42F8IrN4P
Número de CAS:
808142-88-3
Peso molecular:
977.99
UNSPSC Code:
12352101

assay

≥95%

form

powder or crystals

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

photocatalyst activation

450 nm

Categorías relacionadas

Application

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Direct, enantioselective α-alkylation of aldehydes using simple olefins

Photoredox-catalyzed deuteration and tritiation of pharmaceutical compounds

Decarboxylative sp3 C-N coupling via dual copper and photoredox catalysis

related product

Referencia del producto
Descripción
Precios

747769

[Ir(dtbbpy)(ppy)2]PF6

747793

(Ir[dF(CF3)ppy]2(dtbpy))PF6

804215

[Ir{dFCF3ppy}2(bpy)]PF6

901368

[Ir(dFppy)2(dtbbpy)]PF6

901409

[Ir(dF(Me)ppy)2(dtbbpy)]PF6

902217

Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%

902225

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6, ≥95%

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Yufan Liang et al.
Nature, 559(7712), 83-88 (2018-06-22)
Over the past three decades, considerable progress has been made in the development of methods to construct sp2 carbon-nitrogen (C-N) bonds using palladium, copper or nickel catalysis1,2. However, the incorporation of alkyl substrates to form sp3 C-N bonds remains one
Yong Yao Loh et al.
Science (New York, N.Y.), 358(6367), 1182-1187 (2017-11-11)
Deuterium- and tritium-labeled pharmaceutical compounds are pivotal diagnostic tools in drug discovery research, providing vital information about the biological fate of drugs and drug metabolites. Herein we demonstrate that a photoredox-mediated hydrogen atom transfer protocol can efficiently and selectively install
Andrew G Capacci et al.
Nature chemistry, 9(11), 1073-1077 (2017-10-25)
Although the α-alkylation of ketones has already been established, the analogous reaction using aldehyde substrates has proven surprisingly elusive. Despite the structural similarities between the two classes of compounds, the sensitivity and unique reactivity of the aldehyde functionality has typically

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