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Merck

774138

Sigma-Aldrich

Lithium difluoro(oxalato)borate

greener alternative

Sinónimos:

LIDFOB, LIF2OB, LIFOB, LIODFB, Lithium difluoro(ethanedioato)borate, Lithium oxalatodigluoroborate

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About This Item

Fórmula lineal:
LiBF2(C2O4)
Número de CAS:
Peso molecular:
143.77
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23

form

powder

Quality Level

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

265-271 °C

application(s)

battery manufacturing

greener alternative category

SMILES string

F[B-]1(OC(C(O1)=O)=O)F.[Li+]

InChI

1S/C2BF2O4.Li/c4-3(5)8-1(6)2(7)9-3;/q-1;+1

InChI key

MEDDCIKGDMDORY-UHFFFAOYSA-N

General description

Lithium difluoro(oxalato)borate (LIODFB) is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
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Application

Lithium difluorooxalatoborate (LIODFB) is a salt for high-performance Li-ion batteries with improved cycle life; power capability; low temperature and high rate performance of the battery. It has the advantages of both lithium bis(oxalato)borate (LiBOB) and LiBF4. LIODFB also stabilizes the solid electrolyte interface (SEI) on the surface of a graphite anode and is also used as an additive to improve the cycling efficiency and capacity retention of cells
Our battery grade lithium difluorooxalatoborate (LiODFB) is a thermally stable salt and an electrolytic additive for lithium-ion batteries. LIODFB facilitates the formation of stable solid electrolyte interphase (SEI) on the negative electrode, which enhances the cycling efficiency and safety of the battery. Moreover, LiODFB is capable of stabilizing the solid electrolyte interface (SEI) on the surface of lithium metal, graphite, and silicon anode materials, substantially enhances the cyclic performance, capacity and power retention of the electrochemical cells.[5][6][7] In particular, LiODFB is suitable for high-performance Li-ion batteries operating at low temperatures and fast charge and discharge rates.

Features and Benefits

LiODFB improves the efficiency and safety of lithium-ion batteries, allowing them to deliver better performance over a longer time.
✔ Increases battery life
✔ Stabilizes SEI layer
✔ Suitable for fast charging and low temperatures

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Visite la Librería de documentos

Z. Chen;
Electrochemical and Solid-State Letters, 10(3), A45-A45 (2007)
S. Dalavi;
Journal of the Electrochemical Society, 159(5), A642-A642 (2012)
S. S. Zhang;
Electrochemical Communications, 8(9), 1423-1428 (2006)
The Li-ion rechargeable battery: a perspective
Goodenough JB and Park K
Journal of the American Chemical Society, 135(4), 1167-1176 (2013)
Electrodes with high power and high capacity for rechargeable lithium batteries
Kang K, et al.
Science, 311(5763), 977-980 (2006)

Artículos

Dr. Sun reviews the recent advances in solid-state rechargeable batteries and cover the fundamentals of solid electrolytes in solid-state batteries, the theory of ion conduction, and the structures and electrochemical processes of solid-state Li batteries.

Lithium-ion batteries (LIBs) have been widely adopted as the most promising portable energy source in electronic devices because of their high working voltage, high energy density, and good cyclic performance.

The critical technical challenges associated with the commercialization of electric vehicle batteries include cost, performance, abuse tolerance, and lifespan.

Due to the adverse impact of the continued use of fossil fuels on the earth’s environment and climate, researchers have been asked to develop new approaches for producing power using renewable sources like wind and solar energy

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