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Merck

723169

Sigma-Aldrich

Bis[2-(2′-bromoisobutyryloxy)ethyl]disulfide

Sinónimos:

(BiBOE)2S2, ATRP (Bio)degradable Initiator, BiBOEDS

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About This Item

Fórmula empírica (notación de Hill):
C12H20Br2O4S2
Número de CAS:
Peso molecular:
452.22
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

form

liquid

Quality Level

refractive index

n20/D 1.529

density

1.478 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(C)(Br)C(=O)OCCSSCCOC(=O)C(C)(C)Br

InChI

1S/C12H20Br2O4S2/c1-11(2,13)9(15)17-5-7-19-20-8-6-18-10(16)12(3,4)14/h5-8H2,1-4H3

InChI key

PXBWWYBXPGZCHC-UHFFFAOYSA-N

Application

Atom Transfer Radical Polymerisation (ATRP) initiator for the preparation of biodegradable polymers as well as polymers that adhere to gold surfaces. May also be used to introduce a temperature and light sensitive cleavable region into the polymer.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Visite la Librería de documentos

Tsarevsky, N.V.; Matyjaszewski, K.
Macromolecules, 35, 9009-9009 (2002)
Wenjing Huang et al.
Theranostics, 9(13), 3825-3839 (2019-07-10)
Reversing multidrug resistance (MDR) remains a big challenge in cancer therapy. Combining the hyperthermia and chemotherapy is a promising strategy for efficient cancer treatment with MDR reversal. Gold nanocages (GNCs) are an ideal photothermal (PTT)-chemotherapy integration platform due to their
Hao Zhao et al.
ACS nano, 13(6), 6647-6661 (2019-05-16)
Highly efficient nanoarchitectures are of great interest for achieving precise chemotherapy with minimized adverse side effects in cancer therapy. However, a major challenge remains in exploring a rational approach to synthesize spatiotemporally selective vehicles for precise cancer chemotherapy. Here, we

Artículos

Find how atom transfer radical polymerization (ATRP) tools can be used for the synthesis of well-defined functionalized polymers.

Atom transfer radical polymerization (ATRP) has emerged as one of the most successful synthetic techniques for the preparation of polymers with predetermined molecular weights, narrow molecular weight distributions, and high degrees of chain end functionalities.

ATRP polymerization, chain transfer agent, living polymerization, functional telechelic polymers

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

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Protocolos

Sigma-Aldrich presents an article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

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