710733
2,2,5-Trimethyl-4-phenyl-3-azahexane-3-nitroxide
Sinónimos:
1,1-Dimethylethyl-2-methyl-1-phenylpropyl nitroxide, tert-Butyl 1-phenyl-2-methylpropyl nitroxide, NMP universal alkoxyamine nitroxide
About This Item
Productos recomendados
![N-tert-Butyl-O-[1-[4-(chloromethyl)phenyl]ethyl]-N-(2-methyl-1-phenylpropyl)hydroxylamine](/deepweb/assets/sigmaaldrich/product/structures/298/481/e5f98578-0ed3-446e-bed2-e277dfa06e5d/640/e5f98578-0ed3-446e-bed2-e277dfa06e5d.png)
refractive index
n20/D 1.515
density
0.953 g/mL at 25 °C
storage temp.
−20°C
SMILES string
CC(C)C(N([O])C(C)(C)C)c1ccccc1
InChI
1S/C14H22NO/c1-11(2)13(15(16)14(3,4)5)12-9-7-6-8-10-12/h6-11,13H,1-5H3
InChI key
VGHCMXLEZFMZOZ-UHFFFAOYSA-N
General description
Application
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Ox. Liq. 3
Storage Class
5.1B - Oxidizing hazardous materials
wgk_germany
WGK 3
flash_point_f
205.0 °F - closed cup
flash_point_c
96.1 °C - closed cup
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Artículos
Block Copolymer Synthesis Using a Nitroxide-mediated Radical Polymerization (NMP) Approach
Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator
We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.
We presents an article about Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands, and the emergence of living radical polymerization mediated by transition metal catalysts in 1995, which was a seminal piece of work in the field of synthetic polymer chemistry.
Protocolos
Sigma-Aldrich presents an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.
We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.
Sigma-Aldrich presents an article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.
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