683434
(Dimethylphenylsilyl)boronic acid pinacol ester
95%
Sinónimos:
2-(Dimethylphenylsilyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, B-(dimethylphenylsilyl)pinacolborane
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About This Item
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assay
95%
form
liquid
refractive index
n20/D 1.4946
density
0.962 g/mL at 25 °C
SMILES string
CC1(C)OB(OC1(C)C)[Si](C)(C)c2ccccc2
InChI
1S/C14H23BO2Si/c1-13(2)14(3,4)17-15(16-13)18(5,6)12-10-8-7-9-11-12/h7-11H,1-6H3
InChI key
ARMSAQNLTKGMGM-UHFFFAOYSA-N
Categorías relacionadas
Application
(Dimethylphenylsilyl)boronic acid pinacol ester (Suginome′s reagent) can be used as a reagent:
- For the selective addition of dimethylphenylsilanyl group to cyclic and acyclic unsaturated ketones, esters, acrylonitriles using a copper catalyst.
- In the synthesis of (Z)-4-boryl-1-silyl-2-alkene derivatives by stereoselective addition of silicon-boron bond to acyclic 1,3-dienes in presence of Ni catalyst.
- In the preparation of silyl-substituted butenoate and β-silyl-substituted acrylate derivatives from allenes and propiolate derivatives via hydrosilylation reactions using a copper catalyst.
- In the palladium-catalyzed asymmetric silaboration of allenes and alkanes to offered corresponding β-borylallylsilanes and 2-boryl-1-silylalkanes respectively.
Storage Class
10 - Combustible liquids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Los clientes también vieron
Enantioselective conjugate silyl additions to cyclic and acyclic unsaturated carbonyls catalyzed by Cu complexes of chiral N-heterocyclic carbenes.
Journal of the American Chemical Society, 132(9), 2898-2900 (2010)
Geminal Difunctionalization of Alkenylidene?Type Carbenoids by Using Interelement Compounds.
Angewandte Chemie (International Edition in English), 40(4), 790-792 (2001)
Stereoselective 1, 4-silaboration of 1, 3-dienes catalyzed by nickel complexes
Organic Letters, 1(10), 1567-1569 (1999)
Platinum?Catalyzed Regioselective Silaboration of Alkenes.
Angewandte Chemie (International Edition in English), 36(22), 2516-2518 (1997)
Palladium-catalyzed asymmetric silaboration of allenes.
Journal of the American Chemical Society, 128(42), 13682-13683 (2006)
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